文献类型：期刊文献

中文题名：松节油加成反应的研究进展

英文题名：Progress on addition reactions of turpentine oil

作者：廖圣良[1] 商士斌[1] 司红燕[1] 饶小平[1] 宋湛谦[1]

第一作者：廖圣良

机构：[1]中国林业科学研究院林产化学工业研究所、生物质化学利用国家工程实验室国家林业局林产化学工程重点开放性实验室、江苏省生物质能源与材料重点实验室,江苏南京210042

年份：2014

卷号：33

期号：7

起止页码：1856-1863

中文期刊名：化工进展

外文期刊名：Chemical Industry and Engineering Progress

收录：CSTPCD;;Scopus;北大核心:【北大核心2011】；CSCD:【CSCD2013_2014】；

基金：国家自然科学基金云南联合基金项目(U1202265)

语种：中文

中文关键词：松节油;蒎烯;加成反应;衍生物

外文关键词：turpentine;pinene;addition reaction;derivatives

分类号：TQ645.8

摘要：松节油是世界上最主要的植物精油,具有很高的应用价值。α-蒎烯和β-蒎烯是松节油最主要的两个组成成分,以这两个化合物为原料,经过多种化学反应途径,可以合成众多具有高附加值的衍生化合物。然而,目前对上文提及的化学反应途径的系统介绍仍然比较缺乏。本文对α-蒎烯和β-蒎烯经过加成反应合成衍生物的研究进行了综述;介绍了α-蒎烯和β-蒎烯与氢气、水、氯化氢等8类化合物进行加成反应生成衍生物的合成方法的研究,并简述了这些衍生物的应用研究。展望了未来松节油衍生物合成研究的方向,指出合成具有特殊性能的衍生物具有重要意义。
Turpentine oil,the most important essential oil of the world,has a high application value. α-pinene and β-pinene are two principle components of turpentine oil,using these two compounds,plenty of derivatives with high value-added can be synthesized through several reaction pathways. However some systematic introductions to those pathways mentioned above are still deficient. This paper reviewed the research progress on synthesis of derivatives from addition reactions of α-pinene or β-pinene. Methods applied in that α-pinene or β-pinene reacted with eight kind of compounds（including H2,H2O,HCl,etc.） were introduced intensively;applications of the derivatives from these reactions were mentioned as well. Finally,a prospect was given to the future research on synthesis of turpentine oil derivatives;it was believed that synthesis of derivatives with specific properties might be of great importance.