文献类型：会议论文

英文题名：Synthesis, self-assembly and electrochemical behavior of disulphide derivatised mesoporphyrin on gold electrodes

作者：Xu, Shichao[1,2,3,4] Zhao, Zhendong[1,2,3,4] Hu, Bingcheng[5]

第一作者：徐士超;Xu, Shichao

通信作者：Xu, SC[1]

机构：[1]Chinese Acad Forestry, Inst Chem Ind Forest Prod, Nanjing 210094, Jiangsu, Peoples R China;[2]Key Lab Biomass Energy & Mat, Nanjing 210042, Jiangsu, Peoples R China;[3]Natl Engn Lab Biomass Chem Utilizat, Nanjing 210042, Jiangsu, Peoples R China;[4]State Forestry Adm, Key & Open Lab Forest Chem Engn, Nanjing 210042, Jiangsu, Peoples R China;[5]Nanjing Univ Sci & Technol, Sch Chem Engn, Nanjing 210094, Jiangsu, Peoples R China

会议论文集：3rd International Conference on Material, Mechanical and Manufacturing Engineering (IC3ME)

会议日期：JUN 27-28, 2015

会议地点：Guangzhou, PEOPLES R CHINA

语种：英文

外文关键词：Mesoporphyrin disulphide derivative; Self-assembly; Biomimetic electrocatalysis

年份：2015

摘要：Disulphide derivatised mesoporphyrin (DSDMP) and its cobalt complex Co(II) DSDMP were conveniently synthesized and successfully immobilized onto gold surface by monolayer self-assembly of disulfide. The modified electrode was characterized by Infrared Spectrometer (IR) and X-ray photoelectron spectroscopy (XPS) and confirmed electrochemically by cyclic voltammogram (CV) and differential pulse voltammogram (DPV). The characterization results supported the stable formation of Co(II) DSDMP monolayer with a surface coverage of 1.48x10(-10) mol/cm(-2).