详细信息
Thermal degradation and plasticizing mechanism of poly(vinyl chloride) plasticized with a novel cardanol derived plasticizer ( CPCI-S收录 EI收录) 被引量:23
文献类型:会议论文
英文题名:Thermal degradation and plasticizing mechanism of poly(vinyl chloride) plasticized with a novel cardanol derived plasticizer
作者:Chen, J.[1,2,3] Nie, X. A.[1,2,3,4] Jiang, J. C.[1,2,3,4] Zhou, Y. H.[1,2,3,4]
第一作者:Chen, J.
通信作者:Nie, XA[1];Nie, XA[2];Nie, XA[3];Nie, XA[4]|[a0005997aa787f4d4afa0]聂小安;
机构:[1]Chinese Acad Forestry, Inst Chem Ind Forestry Prod, Nanjing 210042, Jiangsu, Peoples R China;[2]Natl Engn Lab Biomass Chem Utilizat, Nanjing 210042, Jiangsu, Peoples R China;[3]Key Lab Biomass Energy & Mat, Nanjing 210042, Jiangsu, Peoples R China;[4]Chinese Acad Forestry, Inst New Technol Forestry, Beijing 100091, Peoples R China
会议论文集:2nd International Conference on New Material and Chemical Industry (NMCI)
会议日期:NOV 18-20, 2017
会议地点:Sanya, PEOPLES R CHINA
语种:英文
外文关键词:Chemical industry - Chlorine compounds - Differential scanning calorimetry - Fourier transform infrared spectroscopy - Glass transition - Plasticizers - Reinforced plastics - Solvents - Thermogravimetric analysis
年份:2018
摘要:A natural plasticizer cardanol derivatives glycidyl ether (CGE) was synthesized and employed as a plasticizer for the poly(vinyl chloride). The effect of CGE on thermal degradation of PVC films and its plasticizing mechanism were firstlyreported. The molecular structure of CGE was characterized with Fourier transform infrared spectroscopy (FTIR). Thermal properties, degradation properties and compatibility of the PVC films were investigated byDifferential scanning calorimeter analysis (DSC), Thermogravimetric analysis (TGA) and FTIR, respectively. Compared with the commercial plasticizers dioctylphthalate (DOP), CGE can endow PVC film with a decrease of 4.31 degrees C in glass transition temperature (Tg), an increase of 24.01 degrees C and 25.53 degrees C in 10% weight loss(T-10) and 50% weight loss (T-50) respectively, and a higher activetion energy of thermal degradation (E-a).
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