文献类型：期刊文献

中文题名：3-蒈烯催化转化反应及应用研究

英文题名：Catalytic Transformation and Application of 3-Carene

作者：王婧[1,2,3,4,5] 杨学兵[6] 赵振东[1,2,3,4,5] 徐士超[1,2,3,4,5] 古研[1,2,3,4] 卢言菊[1,2,3,4,5]

第一作者：王婧

机构：[1]中国林业科学研究院林产化学工业研究所;[2]生物质化学利用国家工程实验室;[3]国家林业局林产化学工程重点开放性实验室;[4]江苏省生物质能源与材料重点实验室;[5]中国林业科学研究院林业新技术研究所;[6]四川省林业科学研究院

年份：2017

卷号：37

期号：1

起止页码：36-42

中文期刊名：林产化学与工业

外文期刊名：Chemistry and Industry of Forest Products

收录：CSTPCD;;Scopus;北大核心:【北大核心2014】；CSCD:【CSCD2017_2018】；

基金：国家林业局林业科学技术推广项目资助([2015]30)

语种：中文

中文关键词：3-蒈烯;催化转化;金属催化剂;ZSM-5型分子筛;间伞花烃

外文关键词：3-carene;catalytic transformation;metal catalyst; ZSM-5 molecular sieves; /n-cymene

分类号：TQ351;TQ654.2

摘要：以建立3-蒈烯的高效利用途径为目的,对其催化转化进行了深入研究,结果表明:金属类催化剂对促进3-蒈烯发生三元环开环脱氢具有很高的活性,尤其是在铂催化下脱氢产物伞花烃的选择性超过90%,其中,间伞花烃与对伞花烃的质量比约为7∶2;分子筛催化同样会导致3-蒈烯发生三元环开环并脱氢,随着反应温度升高,脱氢产物对伞花烃进一步裂解生成甲苯等芳烃化合物,ZSM-5型分子筛在促进裂解反应方面能力突出。在此基础上,建立了以金属铂与ZSM-5型分子筛为复合催化剂,3-蒈烯经连续催化转化制备甲苯与间伞花烃的工艺路线,在V(Pt/Al_2O_3)∶V(ZSM-5)1∶1,280℃的条件下,原料转化率接近100%,产品总得率大于85%,最终产物甲苯得率约25%,纯度大于99%;间伞花烃得率约46%,纯度大于95%。
With the purpose of establishing an application method, studies on the catalytic transformation of 3-carene were carried out. The results indicated that metal catalysts, especially the platinum, had excellent ability to promote the ring opening and dehydrogenation of three-membered ring in 3-carene. With platinum-catalysis, the selectivity of dehydrogenation product cymene exceeded 90% and the mass ratio of m-cymene to p-cymene was nearly 7：2. The ring opening and dehydrogenation of 3-carene could be similarly catalyzed by molecular sieves. However, with the rising of temperature, the dehydrogenation product p-cymene would further be cracked to aromatics like toluene. Molecular sieves ZSM-5 showed a prominent activity in promoting this reaction. On the basis of these results, a continuous process of preparation of toluene and m-cymene from 3-carene was established by using platinum and ZSM-5 as a kind of composite catalyst. The conversion rate of raw material was nearly 100% and the yield of all products was more than 85%. The yield and purity of one of the final products toluene were 25% and 99%, respectively. While m-cymene were 46% and 95%, respectively, with reaction conditions at the volume ratio of Pt/Al2O3 to ZSM-5 1：1 and 280℃.