文献类型：期刊文献

中文题名：梓油酸合成C_(22)二官能度缩水甘油酯型环氧树脂的研究

英文题名：STUDY ON SYNTHESIS OF C_(22) DIGLYCIDYL ESTER TYPE EPOXY RESINS FROM STILLINGIA OIL FATTY ACIDS

作者：聂小安[1] 王定选[1]

第一作者：聂小安

机构：[1]中国林业科学研究院林产化学工业研究所

年份：1998

卷号：13

期号：4

起止页码：9-14

中文期刊名：热固性树脂

外文期刊名：THERMOSETING RESIN

收录：CSTPCD;;CSCD:【CSCD_E2011_2012】；

语种：中文

中文关键词：梓油;环氧树脂;异构化;双烯加成;固化

外文关键词：Stillingia oil resins, Epoxy resins, Isomerization, Diene-addition, Curing reaction

分类号：TQ323.504

摘要：本文以中国特产油脂籽油为原料，通过脂肪酸异构化、双烯加成及酯化闭环等反应，合成了具有粘度小和柔韧性好等特点的C22二官能度缩水甘油酯型环氧树脂，探讨了最佳合成条件及反应规律，环氧树脂得率达90％以上。利用DSC－TG法对产物固化反应行为进行了表征，并对C22二官能度环氧树脂的应用前景进行了分析。
By series of reactions such as isomerization, diene-addition, esterification and ringclosing, the C22 diglycidyl ester type epoxy resin with low viscosity and good flexibility was synthesized from stillingia oil, a special product of China, and the optimal reaction conditions and reaction principle were discussed. Its yields were above 90%. The practical properties of C22 diglycidyl ester type epoxy resins were analysed. The properties of curing reactions of the resins were also characterized by the method of TG-DSC.