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Preparation of water-resistant soybean meal-based adhesives with waste paper cellulose via NaOH/urea pretreatment and oxidation  ( SCI-EXPANDED收录 EI收录)   被引量:18

文献类型:期刊文献

英文题名:Preparation of water-resistant soybean meal-based adhesives with waste paper cellulose via NaOH/urea pretreatment and oxidation

作者:Chang, Zhiwei[1,2] Mo, Liuting[1,2] Huang, Anmin[3] Li, Jianzhang[1,2] Zhang, Shifeng[1,2]

第一作者:Chang, Zhiwei

通信作者:Zhang, SF[1]

机构:[1]Beijing Forestry Univ, MOE Key Lab Wooden Mat Sci & Applicat, Beijing 100083, Peoples R China;[2]Beijing Forestry Univ, Beijing Key Lab Wood Sci & Engn, Beijing 100083, Peoples R China;[3]Chinese Acad Forestry, Res Inst Wood Ind, Beijing 100091, Peoples R China

年份:2020

卷号:27

期号:8

起止页码:4455-4470

外文期刊名:CELLULOSE

收录:;EI(收录号:20201008258437);Scopus(收录号:2-s2.0-85080110066);WOS:【SCI-EXPANDED(收录号:WOS:000516958100001)】;

基金:This work was financially supported by the Fundamental Research Funds for the Central Universities (No. 2016ZCQ01).

语种:英文

外文关键词:Fiber-reinforced; Soybean meal-based adhesives; Alkali-urea system; Oxidation treatment; Mechanical properties

摘要:Fiber agglomeration and poor interfacial combination with the matrix restrict the performance of composites. Herein, soybean meal-based adhesives were fabricated via the addition of dialdehyde cellulose (DAC) obtained from waste paper dissolved in an alkali-urea system and oxidized with sodium periodate. Due to the dissolution by the alkali-urea system, DAC dispersed well in the solution and did not aggregate in the adhesive matrix. Because of the oxidation treatment, DAC was crosslinked with the adhesive matrix via a Schiff base reaction. Meanwhile, hydrogen bonds were formed at the interface between the DAC and the adhesive matrix. Plywood with the SM/DAC/PTGE adhesive reached its highest wet bonding strength of 1.27 MPa (4 wt% DAC addition), a 95% increase compared to that with the unmodified SM/PTGE adhesive. Fine DAC-to-SM interfacial bonding and a dense crosslinking network were constructed in the SM/DAC/PTGE adhesive systems. The cycle of reuse for the alkali-urea system in the experiments demonstrated that the preparation method of the cellulose solution was scalable and sustainable. [GRAPHICS] .

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