文献类型：期刊文献

英文题名：Facilitated fabrication of high strength silica aerogels using cellulose nanofibrils as scaffold

作者：Fu, Jingjing[1,2] Wang, Siqun[2,4] He, Chunxia[1] Lu, Zexiang[2,3] Huang, Jingda[4] Chen, Zhilin[4]

第一作者：Fu, Jingjing

通信作者：He, CX[1];Wang, SQ[2]

机构：[1]Nanjing Agr Univ, Coll Engn, Nanjing 210031, Jiangsu, Peoples R China;[2]Univ Tennessee, Ctr Renewable Carbon, Knoxville, TN 37996 USA;[3]Fujian Agr & Forestry Univ, Coll Chem Engn, Fuzhou 350002, Peoples R China;[4]Chinese Acad Forestry, Res Inst Wood Ind, Beijing 100091, Peoples R China

年份：2016

卷号：147

起止页码：89-96

外文期刊名：CARBOHYDRATE POLYMERS

收录：;EI(收录号：20161702295038);Scopus(收录号：2-s2.0-84963854404);WOS:【SCI-EXPANDED(收录号:WOS:000376449300012)】；

基金：This work was financially supported by the Special Fund for Forest Scientific Research in the Public Welfare (No. 201504603) and the 2014 UTIA Innovation Grant.

语种：英文

外文关键词：Aerogels; Cellulose; Silica; Compression properties; Insulation

摘要：Monolithic cellulose nanofibrils (CNF)-silica composite aerogels were successfully prepared by immersing CNF aerogels into a silica solution in a two-step sol-gel process (initial hydrolysis of tetraethyl orthosilicate (TEOS) followed by condensation of silica particles). Aerogels were characterized by SEM, BET surface area test, bulk density and silica content analysis, FTIR spectroscopy, and compression test. The form of SiO2 existing in the composite aerogel was the spherical individual particles coated on CNF fibrils. The pH value of condensation solution was found to have great influence on the properties of the composite aerogels. By varying the pH value of condensation atmosphere from 8 to 12, the bulk densities of composite aerogels were able to be linearly increased from 0.059 g cm(-3) to 0.29 g cm(-3), and the silica content in the matrix sharply jumped from 3 wt% to 79 wt%. The porosities of the aerogels remained very high, between 85 and 96%, and the surface area of the composite aerogel reached up to 700.1 m(2) g(-1). The compression properties of the composite aerogel improved greatly compared with those of the silica aerogel, about 8-30 times higher. Moreover, the compressive strength of the composite aerogel prepared in this work greatly exceeded the conventional insulation materials found in the recent commercial market, and without substantial increases in thermal conductivity. Hence, the findings of this research offer a promising application for composite aerogels and give a theoretical basis for developing new advanced materials. (C) 2016 Elsevier Ltd. All rights reserved.