文献类型：期刊文献

英文题名：Influence of hygrothermal condition on dynamic viscoelasticity of Chinese fir (Cunninghamia lanceolata). Part 1: moisture adsorption

作者：Zhan, Tianyi[1,2] Jiang, Jiali[1] Lu, Jianxiong[1] Zhang, Yaoli[2] Chang, Jianmin[3]

第一作者：Zhan, Tianyi

通信作者：Lu, JX[1]

机构：[1]Chinese Acad Forestry, Res Inst Wood Ind, State Key Lab Tree Genet & Breeding, Beijing 100091, Peoples R China;[2]Nanjing Forestry Univ, Coll Mat Sci & Engn, Nanjing 210037, Jiangsu, Peoples R China;[3]Beijing Forestry Univ, Coll Mat Sci & Technol, Beijing 100083, Peoples R China

年份：2018

卷号：72

期号：7

起止页码：567-578

外文期刊名：HOLZFORSCHUNG

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000437362700006)】；

基金：This work was financially supported by the National Natural Science Foundation of China (Funder Id: 10.13039/501100001809, No. 31700487), the Natural Science Foundation of Jiangsu Province (CN) (No. BK20170926), the Innovation Fund for Young Scholars of Nanjing Forestry University (CX2017002) and the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD).

语种：英文

外文关键词：hygrothermal conditions; mechano-sorptive effect; moisture adsorption; viscoelasticity

摘要：The dynamic viscoelasticity of Chinese fir was investigated by dynamic mechanical analysis (DMA), while the influence of the moisture adsorption (M-Ads) was the focus of the study. The specimens were climatized at 30, 40, 50, 60, 70 and 80 degrees C under two relative humidity (RH) modes. The RHramp mode included 0, 30, 60 and 90% RH with varied ramping rates (0.5, 1.0 and 2.0% RH min -1 ), while the RHisohume method worked with constant RHs of 30, 60 and 90%, respectively, for 60, 120 or 240 min. During the M-Ads process, a decrease in stiffness and an increase in damping of the wood were seen and were attributed to the combination of the plasticization, mechano-sorptive (MS) effects and heating. High temperatures accelerate the M-Ads pace and intensify the plasticization and MS effects. In RHramp experiments, the glass ram transition RH (RHg) of xylan was visible, as determined by the maximum of damping. The values of RHg varied from 60 to 90% at 50 degrees C or above. In the RHisohume mode, the thermal softening of hemicelluloses and lignin occurred for shorter time periods under more severe hygrothermal (HT) levels between 40-60 degrees C and 70-80 degrees C, respectively. During M-Ads, the MS effect diminished as the wood approached a new equilibrium moisture content (EMC). The M-Ads times to new EMCs became shorter at the expense of intensifying the unstable arrangement of the wood cell wall. Severe HT levels led to great residual instabilities in the wood cell wall, which could be evaluated by the relationship between the extent of the MS effect and the difference between the MC and EMC.