文献类型：期刊文献

中文题名：石墨炉原子吸收光谱法测定保健品松花粉中痕量铅

英文题名：Determination of Trace Lead in Pine Pollen of Health Foods by Graphite Furnace Atomic Absorption Spectrometry

作者：屈明华[1] 汤富彬[1] 倪张林[1]

第一作者：屈明华

机构：[1]中国林业科学研究院亚热带林业研究所,国家林业局经济林产品质量检验检测中心(杭州)

年份：2012

卷号：28

期号：4

起止页码：581-583

中文期刊名：分析科学学报

外文期刊名：Journal of Analytical Science

收录：CSTPCD;;北大核心:【北大核心2011】；CSCD:【CSCD2011_2012】；

语种：中文

中文关键词：铅;保健品;松花粉;石墨炉原子吸收光谱

外文关键词：Lead; Health foods; Pine pollen; Graphite furnace atomic absorption spectrometry

分类号：O657.31

摘要：实验通过采用优级纯以上试剂降低本底,多道程序清洗器皿控制污染,通过控制酸量改善测定铅的信噪比,降低检出限,引入基体改进剂磷酸二氢铵消除基体干扰。优化石墨炉检测条件下,松花粉样品中铅的加入平均回收率达到90%以上。使用标准物质(茶叶GBW10016)对该方法进行了验证,结果表明铅的测定值在标准物质的保证值范围内。该方法能够推广至准确测定花粉类植物性保健品中铅含量。
The experimental conditions of graphite furnace atomic absorption spectrometry were optimized by several means, such as the selection of guaranteed reagent to reduce background, the use of multiple cleaning of glass ware to control pollute, the control of acid content to ensure sensitivity, and the adoption of NH4H2PO4 as the matrix modifier to clear up matric interference. Under the optimized conditions, a Pb recovery of up to 90~ was obtained. The method was applied to the determination of Pb in a certified reference material （tea leaves GBW 10016） and the results obtained agreed well with the certified value. The method could potentially be used in the determination of Pb in pine pollen samples.