文献类型：期刊文献

中文题名：Synthesis and Crystal Structure of a Degraded Dehydroabietylamine Thiophene Imine

英文题名：Synthesis and crystal structure of a degraded dehydroabietylamine thiophene imine

作者：Rao Xiao-Ping[1] Song Zhan-Qian[1] Wu Yong[1] Jia Wei-Hong[1] Shang Shi-Bin[1]

第一作者：饶小平

通信作者：Song, ZQ[1]

机构：[1]Chinese Acad Forestry, Inst Chem Ind Forest Prod, Nanjing 210042, Peoples R China

年份：2008

卷号：27

期号：7

起止页码：884-887

中文期刊名：结构化学

外文期刊名：CHINESE JOURNAL OF STRUCTURAL CHEMISTRY

收录：;Scopus(收录号：2-s2.0-76349097108);WOS:【SCI-EXPANDED(收录号:WOS:000258436900023)】；北大核心:【北大核心2004】；CSCD:【CSCD2011_2012】；

基金：This research was financially supported by the grants from Forestry Common Wealth Industry Special Foundation of China (No. 200704008) and National Natural Science Foundation of China (No. 30771690)

语种：英文

中文关键词：合成;晶体结构;脱氢松香胺噻吩;X射线衍射分析

外文关键词：degraded dehydroabietylamine thiophene imine; synthesis; crystal structure

分类号：O626

摘要：A degraded dehydroabietylamine thiophene imine (C24H30NS, Mr = 364.55) has been synthesized from dehydroabietic acid, and its structure was characterized by IR, 1H NMR spectroscopy and single-crystal X-ray diffraction. White crystals of the title compound crystallize in the monoclinic system, space group P21 with a = 5.9490(12), b = 16.337(3), c = 10.780(2), β = 92.21(3)o, V = 1046.9(3) 3, Z = 2, Dc = 1.156 g/cm3, λ = 0.71073 , μ = 0.162 mm-1, F(000) = 394, the final R = 0.0443 and wR = 0.0805 for 1325 observed reflections with I > 2σ(I). The imine group was directly attached to the chiral carbon atom of tricyclo hydrophenthenrane structure with a trans configuration. The dihedral angle between two aromatic rings is 88.3o.
A degraded dehylroabietylamine thiophene imine (C24H30NS, M-r = 364.55) has been synthesized from dehydroabietic acid, and its structure was characterized by IR, H-1 NMR spectroscopy and single-crystal X-ray diffraction. White crystals of the title compound crystallize in the monoclinic system, space group P2(1) with a = 5.9490(12), b = 16.337(3), c = 10.780(2) angstrom, 92.21(3)degrees, V = 1046.9(3) angstrom(3), Z = 2, D-c = 1.156 g/cm(3), A = 0.71073 angstrom, mu = 0.162 mm(-1), F(000) = 394, the final R = 0.0443 and wR = 0.0805 for 1325 observed reflections with I > 2 sigma(I). The imine group was directly attached to the chiral carbon atom of tricyclo hydrophenthenrane structure with a trans configuration. The dihedral angle between two aromatic rings is 88.3 degrees.