文献类型：期刊文献

英文题名：A Strategy for Nonmigrating Plasticized PVC Modified with Mannich base of Waste Cooking Oil Methyl Ester

作者：Jia, Puyou[1,2,3,4] Zhang, Meng[1,2,3,4] Hu, Lihong[1,2,3,4] Song, Fei[1,2,3,4] Feng, Guodong[1,2,3,4] Zhou, Yonghong[1,2,3,4]

第一作者：Jia, Puyou;贾普友

通信作者：Zhang, M[1];Zhou, YH[1];Zhang, M[2];Zhou, YH[2];Zhang, M[3];Zhou, YH[3];Zhang, M[4];Zhou, YH[4]

机构：[1]Chinese Acad Forestry, Inst Chem Ind Forest Prod, 16 Suojin North Rd, Nanjing 210042, Jiangsu, Peoples R China;[2]Natl Engn Lab Biomass Chem Utilizat, 16 Suojin North Rd, Nanjing 210042, Jiangsu, Peoples R China;[3]State Forestry Adm, Key Lab Forest Chem Engn, 16 Suojin North Rd, Nanjing 210042, Jiangsu, Peoples R China;[4]Key Lab Biomass Energy & Mat, 16 Suojin North Rd, Nanjing 210042, Jiangsu, Peoples R China

年份：2018

卷号：8

期号：1

外文期刊名：SCIENTIFIC REPORTS

收录：;Scopus(收录号：2-s2.0-85041078820);WOS:【SCI-EXPANDED(收录号:WOS:000423422700008)】；

基金：National Natural Science Foundation of China (Grant Nos 31700499, 31670578 and 31670577); This work was supported by the Fundamental Research Funds from Jiangsu Province Biomass and Materials Laboratory (JSBEM-S-2017010).

语种：英文

摘要：The waste cooking oil (WCO) production from the catering industry and food processing industry causes serious environmental, economic and social problems. However, WCO can be used for the preparation of fine chemicals such as internal plasticizer. With this aim, this work is focused on preparing internal plasticizer by using WCO and determining technical viability of non-migration poly (vinyl chloride) (PVC) materials. The mannich base of waste cooking oil methyl ester (WCOME) was synthesized from WCO via esterification, interesterification and mannich reaction, which was used to produce self-plasticization PVC materials as an internal plasticizer. The results showed that the PVC was plasticized effectively. Self-plasticization PVC films showed no migration in n-hexane, but 15.7% of dioctyl phthalate (DOP) leached from DOP/PVC(50/50) system into n-hexane. These findings transformed the traditional plastic processing technology and obtained cleaner production of no migration plasticizer from WCO.