文献类型：期刊文献

英文题名：Amino-Functionalized Wood Aerogel for Efficient Removal of Copper Ions from Water

作者：Meng, Junwang[1] Guan, Hao[1] Dai, Xinjian[1] Wang, Xiaoqing[1]

第一作者：Meng, Junwang

通信作者：Wang, XQ[1]

机构：[1]Chinese Acad Forestry, Res Inst Wood Ind, Beijing 100091, Peoples R China

年份：2021

卷号：2021

外文期刊名：INTERNATIONAL JOURNAL OF POLYMER SCIENCE

收录：;EI(收录号：20214511124433);Scopus(收录号：2-s2.0-85108978867);WOS:【SCI-EXPANDED(收录号:WOS:000669919500001)】；

基金：This work was financially supported by the Fundamental Research Funds for the Central Non-profit Research Institution of CAF (CAFYBB2020QA004).

语种：英文

外文关键词：Adsorbents - Adsorption - Aerogels - Cellulose - Chemicals removal (water treatment) - Copper compounds - Costs - Delignification - Heavy metals - Isotherms - Lamellar structures - Metal ions - Monolayers - Musculoskeletal system - Oxidation - Porosity

摘要：Developing bio-based adsorbents for efficient removal of heavy metal ions from water has attracted increasing attention due to their abundance, low cost, and sustainability. However, most of these adsorbents are in powdered or granular forms, suffering from difficult regeneration and poor recyclability. Here, we report a highly porous three-dimensional amino-functionalized wood aerogel for efficient heavy metal adsorption. The amino-functionalized wood aerogel was prepared from natural balsa wood via a delignification treatment, followed by TEMPO-mediated oxidation of the delignified wood and then grafting polyethylenimine (PEI) onto the oxidized cellulose skeleton. The obtained amino-functionalized wood aerogel possessed a unique porous lamellar structure with a low bulk density of 77.2 mg/cm(3) and high porosity of 94.9%. Benefiting from its high porosity and the introduced amino groups on the cellulose skeleton, the amino-functionalized wood aerogel exhibited a maximum Cu(II) adsorption capacity of 59.8 mg.g(-1), which was significantly higher than those of the TEMPO-oxidized wood aerogel and natural balsa wood. The adsorption process can be well described by the pseudo-second-order and Langmuir isotherm models, indicating that the Cu(II) adsorption by the PEI@wood aerogel was dominated by a monolayer chemisorption process. The developed amino-functionalized wood aerogel provides new insights for the design of efficient and low-cost monolithic absorbents for heavy metal remediation.