文献类型：期刊文献

中文题名：木质素磺酸盐与丙烯酸类单体的接枝共聚研究(英文)

英文题名：STUDY ON GRAFT-COPOLYMERIZATION OF CRUDE LIGNOSULFONATES WITH ACRYLIC MONOMERS

作者：李建法[1] 宋湛谦[1] 商士斌[1] 吕金红[2]

第一作者：李建法

机构：[1]中国林业科学研究院林产化学工业研究所;[2]绍兴文理学院化学系

年份：2004

卷号：24

期号：3

起止页码：1-6

中文期刊名：林产化学与工业

外文期刊名：Chemistry & Industry of Forest Products

收录：CSTPCD;;Scopus;CSCD:【CSCD_E2011_2012】；

基金：国家"十五"科技攻关项目资助 (2 0 0 2BA5 17A 0 9 0 5 )

语种：中文

中文关键词：木质素磺酸盐;接枝共聚;丙烯酸类单体

外文关键词：lignosulfonate; graft copolymerization; acrylic monomers

分类号：TQ351.013

摘要：研究了木质素磺酸盐粗产品与丙烯酸类单体的接枝共聚反应 ,对其反应机理进行了评述 ,并采用红外光谱分析证实了聚合反应的发生。与现有的对纯化木质素磺酸盐的研究结果不同 ,粗产品的接枝共聚反应可以单纯由过氧化氢引发 ,原因可能是粗产品中含有的还原性物质起到了亚铁离子的作用。研究表明 ,合适的引发剂用量应该是木质素磺酸盐干重的 1.5 %～ 2 .0 % ,当反应体系中引发剂用量充分时 ,反应温度和时间对产物粘度的影响不明显。产物的粘度随丙烯酸类单体用量的增加而提高 ,在相同单体用量下 ,丙烯酰胺改性产物的粘度高于丙烯酸改性产物 。
Graft copolymerization of crude lignosulfonates with acrylic monomers was investigated,its mechanism was reviewed,and the occurrence of polymerization was confirmed by IR determination.Differing from pure lignosulfo-(nates),graft copolymerization of crude lignosulfonates with acrylic monomers could be initiated solely by hydroperoxide at 1.5%-2.0%(mass ratio) of dry lignosulfonates.With sufficient initiator in the reaction solution,the influence of reaction temperature and time on viscosity of products was not apparent.Viscosity of final products was increased (following) the increase of monomers dosage.At the same dosage, products modified with acrylamide(AM) had higher viscosity than those with acrylic acid(AA),because amide groups on AM polymers is less hydrophilic than carboxylic groups on AA polymers.