文献类型：期刊文献

中文题名：羟甲基化秸秆乙醇残渣脲醛复合树脂的制备与应用性能

英文题名：Preparation and Performance of Hydroxymethylated Straw Ethanol Residue/Urea-formaldehyde Composite Resin

作者：胡岚方[1,2,3,4] 高士帅[1,2,3,4] 赵临五[1,2,3,4] 王春鹏[1,2,3,4,5] 储富祥[6]

第一作者：胡岚方

通信作者：Wang, Chun-Peng|[a00059c51513eb073c331]王春鹏;

机构：[1]中国林业科学研究院林产化学工业研究所;[2]生物质化学利用国家工程实验室;[3]国家林业局林产化学工程重点开放性实验室;[4]江苏省生物质材料与能源重点实验室;[5]中国林业科学研究院林业新技术研究所;[6]中国林业科学研究院

年份：2015

卷号：35

期号：6

起止页码：21-26

中文期刊名：林产化学与工业

外文期刊名：Chemistry and Industry of Forest Products

收录：CSTPCD;;EI(收录号：20161202132613);Scopus(收录号：2-s2.0-84960949902);北大核心:【北大核心2014】；CSCD:【CSCD2015_2016】；

基金：林业公益性行业专项(201304606)

语种：中文

中文关键词：秸秆乙醇残渣;羟甲基化;脲醛树脂;复合树脂

外文关键词：straw ethanol residue ; hydroxymethylation ; urea-formaldehyde resin ; composite resin

分类号：TQ35;TQ433.3

摘要：以秸秆乙醇残渣（ER）为原料，采用羟甲基化反应制备羟甲基化ER（HER），将HER与脲醛树脂（ur）复合制备秸秆乙醇残渣脲醛复合树脂（HER／UF），对制备条件进行了探讨，通过FT-IR对ER和HER中的木质素进行表征，并通过SEM测试对HER在UF中的分散性进行研究。研究结果表明：HER的羟甲基含量较ER的羟甲基含量有所增加，随着ER用量（以甲醛质量计）增大，HER的羟甲基增加量减少；且HER较ER在uF中具有更好的分散性。ER在其用量为2000％，NaOH用量（以HER质量计）0．9％的反应体系下，制备的HER综合性能最好，游离甲醛为0．24％，黏度为3200mPa·S. HER替代10％-40％UF时制备的三合板胶合强度均满足Ⅱ类板的要求，甲醛释放量达到E0级，其中HER替代30％UF制备的三合板性能最好。
The hydroxymethylated straw ethanol residue（HER） was prepared from the hydroxymethylation of straw ethanol residue （ER）. HER and urea-formaldehyde resin （UF） were then blended to fabricate the HER/UF and the preparation conditions were studied. Lignin in ER and HER were characterized by FT-IR and the dispersibilities of ER and HER in UF were analyzed by SEM. The results showed that the content of hydroxymethyl group in HER was more than that in ER. The increment of hydroxymethyl group in HER decreased with the ER dosage（ the mass ratio of ER to formaldehyde） increasing. And HER showed better dispersity compared with ER in the UF resin. The HER prepared under the conditions of 2 000% ER dosage and 0.9% NaOH dosage（ the mass ratio of NaOH to HER） had the best performance. Its free formaldehyde was 0.24% and the viscosity was 3 200 mPa＇s. When 10%-40% UF resin was replaced by HER,formaldehyde emission of the three-ply boards could meet E0 grade and its bonding strength could meet the requirement of type II plywood. And the three-ply board that made by 30% HER/UF had the best performance.