文献类型：期刊文献

英文题名：Synthesis and evaluation of a novel N-P-containing oil-based fire-retardant plasticizer for poly(vinyl chloride)

作者：Jia, Pu-you[1] Feng, Guo-dong[1,2] Hu, Yun[1] Zhou, Yong-hong[1,3]

第一作者：贾普友

通信作者：Zhou, YH[1];Zhou, YH[2]

机构：[1]Chinese Acad Forestry, Inst Chem Ind Forestry Prod, Nanjing, Jiangsu, Peoples R China;[2]Jiangsu Qianglin Bioenergy & Biomat Ltd Co, Liyang, Jiangsu, Peoples R China;[3]Chinese Acad Forestry, Inst New Technol Forestry, Beijing, Peoples R China

年份：2016

卷号：40

期号：1

起止页码：65-75

外文期刊名：TURKISH JOURNAL OF CHEMISTRY

收录：;Scopus(收录号：2-s2.0-84958966793);WOS:【SCI-EXPANDED(收录号:WOS:000368558900013)】；

基金：The authors would like to thank the "State Science and Technology Support Plan" (2012BAD32B05) and the "Commonwealth Research of CAF" (CAFINT2013K01) for financial support during this investigation.

语种：英文

外文关键词：Soybean oil; flame retardant; plasticizer; PVC; SEM

摘要：A novel N-P-containing soybean-oil-based fire-retardant plasticizer was synthesized using soybean oil methyl ester, 9,10-dihydro-9-oxa-phosphaphenanthrene-10-oxide (DOPO), and tris(2-hydroxyethyl) isocyanurate (THEIC). The structure was verified by Fourier transform infrared (FTIR) spectrometry and nuclear magnetic resonance (NMR) spectroscopy. The blends were characterized by thermogravimetric analysis (TGA), FTIR spectrometry, scanning electron microscopy (SEM), and dynamic mechanical analysis (DMA). TGA showed that the thermal stability of the blends were acceptable. DMA indicated that the plasticizer had good plasticity for PVC. The limiting oxygen index (LOI) of the blends ranged from 21.3 to 29.6. The flammability and thermal stability of PVC/THEIC-DOPO-ESOME was better than that of PVC/TCPP.