文献类型：期刊文献

英文题名：Cu(II)/TBAI-Catalyzed Esterification of Acid Hydrazides via C(sp(3))-H Oxidative Coupling

作者：Liu, Guifeng[1,2] Jin, Can[1,2] Wu, Guomin[1,2]

第一作者：刘贵锋

通信作者：Liu, GF[1]

机构：[1]Chinese Acad Forestry, Key Lab Biomass Energy & Mat Jiangsu Prov, Key & Open Lab Forest Chem Engn,State Forestry Ad, Inst Chem Ind Forest Prod,Natl Engn Lab Biomass C, Nanjing 210042, Jiangsu, Peoples R China;[2]Chinese Acad Forestry, Res Inst New Technol, Beijing 10091, Peoples R China

年份：2014

卷号：25

期号：20

起止页码：2908-2912

外文期刊名：SYNLETT

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000345902500014)，CCR-EXPANDED(收录号:WOS:000345902500014)】；

基金：The authors are grateful for the support of the Special Fund for Fundamental Research from the Institute of New Technology of the Chinese Academy of Forestry (CAFINT2012C04).

语种：英文

外文关键词：Cu2+/TBAI cocatalysis; direct coupling; acid hydrazides

摘要：A Cu2+/TBAI-cocatalyzed allylic ester synthesis was developed, which allows a direct coupling of acid hydrazides and cycloalkanes. This process makes use of commercially available, inexpensive, and abundant starting materials. Based on the extensive experimental data, a plausible radical mechanism was suggested.