文献类型：期刊文献

英文题名：Magnetically recyclable Cr complex for the dehydration of glucose to 5-HMF in acidic task specific ionic liquid

作者：Fu, Fei[1,2] Shen, Minggui[1,3] Shang, Shibin[1,3] Song, Zhanqian[1] Wang, Liang[4]

第一作者：Fu, Fei

通信作者：Shen, MG[1];Shen, MG[2];Wang, L[3]|[a0005144160c55dbead8b]沈明贵;

机构：[1]Chinese Acad Forestry, Natl Engn Lab Biomass Chem Utilizat, Key & Open Lab Forest Chem Engn,Inst Chem Ind For, State Forestry Adm,Key Lab Biomass Energy & Mat, Nanjing 210042, Jiangsu, Peoples R China;[2]Nanjing Forestry Univ, Coinnovat Ctr Efficient Proc & Utilizat Forest Re, Nanjing 210037, Jiangsu, Peoples R China;[3]Chinese Acad Forestry, Inst New Technol Forestry, Beijing 100091, Peoples R China;[4]Changzhou Univ, Jiangsu Key Lab Adv Catalyt Mat & Technol, Sch Petrochem Engn, Changzhou 213164, Peoples R China

年份：2019

卷号：9

期号：9

外文期刊名：AIP ADVANCES

收录：;EI(收录号：20193807440482);Scopus(收录号：2-s2.0-85072185010);WOS:【SCI-EXPANDED(收录号:WOS:000488516200034)】；

基金：The authors thank for the financial support by Natural Science Foundation of Jiangsu Province of China (BK20150071), Jiangsu Key Laboratory for Biomass Energy and Material (JSBEM201806), the China Postdoctoral Science Foundation (2018M632289).

语种：英文

外文关键词：Atomic emission spectroscopy - Catalysts - Energy dispersive spectroscopy - Glucose - Inductively coupled plasma - Ionic liquids - Iron oxides - Magnetite - Transmission electron microscopy - X ray diffraction analysis

摘要：Magnetically recyclable Cr complex was synthesized by immobilizing Cr-3(CH3COO)(7)(OH)(2) onto the surface of amino modified Fe3O4 particles. The structure of the catalyst was well characterized by Fourier transform infrared (FT-IR), Transmission electron microscope (TEM), Inductively coupled plasma atomic emission spectroscopy (ICP-AES), Energy dispersive X-ray spectroscopy (EDX), Thermal gravity analysis (TG-ATG), Wide-angle X-ray Diffractometry (XRD) and Vibrating Sample Magnetometer (VSM). The prepared catalyst showed good catalytic performance in the conversion of glucose to HMF in acidic task specific ionic liquid (TSIL). Moreover, the catalyst could be magnetically recovered and for successive six runs without significant decrease in its activity.