文献类型：期刊文献

英文题名：A comprehensive review of covalent organic frameworks (COFs) and their derivatives in environmental pollution control

作者：Ge, Shengbo[1] Wei, Kexin[1] Peng, Wanxi[2] Huang, Runzhou[1] Akinlabi, Esther[3] Xia, Hongyan[4] Shahzad, Muhammad Wakil[3] Zhang, Xuehua[5] Xu, Ben Bin[3] Jiang, Jianchun[6]

第一作者：Ge, Shengbo

通信作者：Huang, RZ[1];Peng, WX[2];Xu, BB[3];Jiang, JC[4]

机构：[1]Nanjing Forestry Univ, Coll Mat Sci & Engn, Coinnovat Ctr Efficient Proc & Utilizat Forest Res, Nanjing 210037, Peoples R China;[2]Henan Agr Univ, Sch Forestry, Zhengzhou 450002, Peoples R China;[3]Northumbria Univ, Dept Mech & Construct Engn, Newcastle Upon Tyne NE1 8ST, England;[4]Northumbria Univ, Dept Appl Sci, Newcastle Upon Tyne NE1 8ST, England;[5]Univ Alberta, Dept Chem & Mat Engn, Edmonton, AB T6G 1H9, Canada;[6]Chinese Acad Forestry, Inst Chem Ind Forest Prod, Jiangsu Coinnovat Ctr Efficient Proc & Utilizat Fo, Key Lab Biomass Energy & Mat Jiangsu Prov, Nanjing 210042, Peoples R China

年份：2024

卷号：53

期号：23

起止页码：11259-11302

外文期刊名：CHEMICAL SOCIETY REVIEWS

收录：;EI(收录号：20244617358718);Scopus(收录号：2-s2.0-85208654577);WOS:【SCI-EXPANDED(收录号:WOS:001345095500001)】；

基金：S. G. R. H., B. B. X. and J. J. developed the scope. S. G., K. W., W. P., R. H. and X. Z. performed literature search and completed the analysis. S. G., K. W., W. P., R. H., E. A., H. X., M. S., X. Z. and B. B. X. processed the figures and visualizations. The work was supervised by S. G., R. H., B. B. X. and J. J. The manuscript was written and revised by S. G., E. A., R. H., X. H., X. Z., B. B. X. and J. J., with contributions from all authors. The authors thank the National Natural Science Foundation of China (32201491), Young Elite Scientists Sponsorship Program by CAST (2023QNRC001), Key Research and Development Program of Jiangsu Province (BE2023361), and Strategic Research and Consulting Project of Chinese Academy of Engineering (2024-XZ-49). B. B. X. is grateful for the support from the Engineering and Physical Sciences Research Council (EPSRC, UK) RiR grant - RIR18221018-1.

语种：英文

外文关键词：Air pollution - Air pollution control - Direct air capture - Environmental management - Soil pollution - Soil pollution control - Ultrasonic applications - Water pollution - Water pollution control

摘要：Covalent organic frameworks (COFs) have gained considerable attention due to their design possibilities as the molecular organic building blocks that can stack in an atomically precise spatial arrangement. Since the inception of COFs in 2005, there has been a continuous expansion in the product range of COFs and their derivatives. This expansion has led to the evolution of three-dimensional structures and various synthetic routes, propelling the field towards large-scale preparation of COFs and their derivatives. This review will offer a holistic analysis and comparison of the spatial structure and synthesis techniques of COFs and their derivatives. The conventional methods of COF synthesis (i.e., ultrasonic chemical, microwave, and solvothermal) are discussed alongside the synthesis strategies of new COFs and their derivatives. Furthermore, the applications of COFs and their derived materials are demonstrated in air, water, and soil pollution management such as gas capture, catalytic conversion, adsorption, and pollutant removal. Finally, this review highlights the current challenges and prospects for large-scale preparation and application of new COFs and the derived materials. In line with the United Nations Sustainable Development Goals (SDGs) and the needs of digital-enabled technologies (AI and machine learning), this review will encompass the future technical trends for COFs in environmental pollution control.