文献类型：期刊文献

中文题名：脱氢枞胺水杨醛类Schiff碱的光致变色和溶致变色性能的研究

英文题名：Study on Photochromic and Solvatochromic Properties of Dehydroabietylamine Salicylidene Schiff Base

作者：饶小平[1,2] 宋湛谦[1,2] 高宏[1,2]

第一作者：饶小平

机构：[1]中国林业科学研究院林产化学工业研究所;[2]国家林业局林产化学工程重点开放性实验室

年份：2006

卷号：26

期号：2

起止页码：27-29

中文期刊名：林产化学与工业

外文期刊名：Chemistry and Industry of Forest Products

收录：CSTPCD;;EI(收录号：20063210056480);Scopus(收录号：2-s2.0-33746781717);CSCD:【CSCD_E2011_2012】；

语种：中文

中文关键词：脱氢枞胺水杨醛Schiff碱;脱氢枞胺(5-硝基)水杨醛Schiff碱;光致变色;溶致变色

外文关键词：dehydroabietylamine salicylidene Schiff base; dehydroabietylamine 5-nitrylsalicylidene Schiff base ; photochromism ; solvatochromism

分类号：TQ351.47

摘要：以乙醇为溶剂合成了脱氢枞胺水杨醛Sch iff碱(a)以及脱氢枞胺(5-硝基)水杨醛Sch iff碱(b),IR光谱确证其结构,用紫外-可见吸收光谱研究了它们在有机溶剂中的光致变色及溶致变色性能。研究发现,a和b在氯仿溶液中都能发生光致变色现象,b在二甲基甲酰胺(DMF)溶液中发生溶致变色现象,讨论了两种物质发生变色现象的机理。
Dehydroabietylamine salicylidene Schiff base （a） and dehydroabietylamine 5-nitrylsalicylidene Schiff base （b） were prepared in ethanol solvent. Their structures were characterized by IR spectroscopy. Their photochromic and solvatochromic properties in organic solvents were studied by UV-Vis spectroscopy. It has been found that： both a and b exhibited photochromism in chloroform solution. Base b exhibited solvatochromism in DMF solution. The mechanisms of photochromism and solvachromism of these two compounds were discussed.