文献类型：期刊文献

中文题名：从脂肪酸的尿素包合法固相物中回收尿素的工艺

英文题名：Technology of recovering urea from urea inclusion compounds producted in the separation of fatty acids using urea complexation

作者：吕微[1] 蒋剑春[1] 徐俊明[1]

第一作者：吕微

机构：[1]中国林业科学研究院林产化学工业研究所生物质化学利用国家工程实验室国家林业局林产化学工程重点开放性实验室江苏省生物质能源与材料重点实验室

年份：2012

卷号：31

期号：1

起止页码：201-207

中文期刊名：化工进展

外文期刊名：Chemical Industry and Engineering Progress

收录：CSTPCD;;Scopus;北大核心:【北大核心2011】；CSCD:【CSCD2011_2012】；

基金：国家林业局公益性行业专项经费(200904008);国家林业局公益性行业专项经费(201104046)项目;国家863计划(2010AA101602)

语种：中文

中文关键词：尿包固相物;混合溶剂;回收,尿素;脂肪酸;尿素包合法

外文关键词：urea inclusion compounds; mixed solvent; recovery urea; fatty acids; urea adduction fractionation

分类号：TQ644

摘要：比较5种回收尿素包合法固相物中的脂肪酸和尿素的方法,其中,甲醇和甲苯的混合溶剂法的回收效果最好。当尿包固相物∶甲醇∶甲苯(g∶mL∶mL)用量比为1∶3∶3时,脂肪酸和尿素的回收率分别为99.12%、99.46%。对回收脂肪酸进行FT-IR、GPC和GC-MS分析:回收的脂肪酸中含有饱和脂肪酸和不饱和脂肪酸(Unsaturated Fatty Acids,UFAs)结构;回收脂肪酸相对分子质量为443,含量93.92%;UFAs含量为93.96%。回收尿素的EMS微观结构分析:回收尿素为针状透明晶体结构和良好的结晶度。考察了回收尿素多次分离多不饱和脂肪酸的效果,重复回收和利用的结果显示:回收尿素6次分离得到的产品中PUFAs含量在81%～89%、UFAs含量为100%、收率在60%～72%。
The technology using methanol-toluene binary solvent mixtures to recover urea and fatty acids from urea inclusion compounds was chosen as the best method through comparative experiments among five kinds of processes.The recovered yields of fatty acids and urea were 99.12% and 99.46% respectively,when the ratio of urea inclusion compounds-methanol-toluene was 1∶3∶3（g∶mL∶ mL）.Recovered fatty acids was analyzed using FT-IR,GPC and GC-MS.FT-IR spectroscopy identified the structure of recovery material,finding that both saturated and unsaturated fatty acids were contained.Relative molecular weight of recovery fatty acids was 443 with a content of 93.92%.Six kinds of fatty acids were identified and content of UFAs（93.96%）were detected in recovery fatty acids via GC-MS.In recovered urea,long needle-like cylindrical crystal structure was observed using SEM,with a better crystallinity.Recovered urea reused for isolating PUFAs were investigated six times.The contents and yields of PUFAs purified by recovery urea were among 81%～89% and 60%～72% respectively,and the purity of UFAs was 100%.