文献类型：期刊文献

英文题名：Synthesis and application of a novel environmental plasticizer based on cardanol for poly(vinyl chloride)

作者：Chen, Jie[1] Li, Xiaoying[1] Wang, Yigang[1] Li, Ke[1] Huang, Jinrui[1] Jiang, Jianchun[1,2] Nie, Xiaoan[1,2]

第一作者：陈洁

通信作者：Jiang, JC[1];Nie, XA[2]|[a0005997aa787f4d4afa0]聂小安;

机构：[1]Chinese Acad Forestry, Inst Chem Ind Forestry Prod, Nanjing 210042, Jiangsu, Peoples R China;[2]Chinese Acad Forestry, Inst New Technol Forestry, Beijing 100091, Peoples R China

年份：2016

卷号：65

起止页码：488-497

外文期刊名：JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS

收录：;EI(收录号：20162502504236);Scopus(收录号：2-s2.0-84973872919);WOS:【SCI-EXPANDED(收录号:WOS:000380624500049)】；

基金：The authors are grateful for the financial support from National "Twelfth Five-Year" Plan for Science & Technology Support (Grant number: 2015BAD15B08), Key Laboratory of Biomass Energy and Materials of Jiangsu Province (Grant number: JSBEM-S-201604).

语种：英文

外文关键词：Poly(vinyl chloride) (PVC); Plasticizer; Cardanol; Renewable resources

摘要：A novel epoxidized cardanol phenyl phosphate ester plasticizer (ECPhP) based on cardanol was synthesized and characterized with H-1 NMR and C-13 NMR. Poly(vinyl chloride) (PVC) films plasticized with ECPhP as plasticizer were prepared. Thermal properties, mechanical properties and migration stability of PVC films were investigated with TGA, TGA-MS, DMA, dynamic thermal stability analysis, and tensile, volatility, extraction and exudation tests. Properties of the PVC films were explored and compared to those of petroleum-based plasticizer dioctyl terephthalate (DOTP). The results indicated that the epoxidized cardanol based phosphate ester had significantly higher thermal stability than DOTP, which could also improve thermal properties of PVC blends obviously. Furthermore, ECPhP could endow PVC resin with well-balanced properties of flexibility, strength and hardness. With the substitution of ECPhP into DOTP, migration resistance of PVC blends was enhanced which was mainly due to the increase of molecular weight. In addition, the thermal degradation processes of PVC films and possible interaction between plasticizers and PVC molecular were also discussed. (C) 2016 Taiwan Institute of Chemical Engineers. Published by Elsevier B.V. All rights reserved.