文献类型：期刊文献

中文题名：压敏胶用含氢化松香酯核/壳型丙烯酸酯乳液的制备

英文题名：Preparation of core/shell-acrylate emulsion with hydrogenated rosin ester for PSA

作者：张开涛[1] 王丹[1,2] 商士斌[1,2] 沈明贵[1]

第一作者：张开涛

机构：[1]中国林业科学研究院林产化学工业研究所,生物质化学利用国家工程实验室,国家林业局林产化学工程重点开放性实验室,江苏省生物质能源与材料重点实验室,江苏南京210042;[2]中国林业科学研究院林业新技术研究所,北京100091

年份：2015

卷号：24

期号：12

起止页码：1-5

中文期刊名：中国胶粘剂

外文期刊名：China Adhesives

收录：CSTPCD;;北大核心:【北大核心2014】；

基金：国家科技支撑项目(2011BAD33B02);国家自然科学基金项目(31170540);江苏省自然科学基金项目(BK2011111)

语种：中文

中文关键词：压敏胶;核/壳型丙烯酸酯;氢化松香酯;细乳液

外文关键词：pressure sensitive adhesive （PSA） ; core/shell-acrylate ; hydrogenated rosin ester; mini-emulsion

分类号：TQ331.47;TQ436.3

摘要：采用细乳液两步法制备PSA（压敏胶）用松香衍生物包覆的核/壳型丙烯酸酯乳液。着重探讨了细乳液的聚合条件、氢化松香二甘醇酯（HR-DGE）掺量等对乳液及其PSA性能的影响。研究结果表明：PSA用乳液的最佳聚合条件是w（HR-DGE）=5%、w（APS）=0.8%（均相对于单体总质量而言）、保温时间为2~3 h和保温温度为85℃,此时单体转化率相对最高（〉95%）;当w（HR-DGE）=4%时,PSA的初粘力和持粘力俱佳;随着HR-DGE掺量的增加,PSA用乳液对BOPP薄膜的润湿性增大、相对分子质量（Mr）下降、Mr分布变窄和玻璃化转变温度（Tg）呈先降后升态势,并且PSA的初粘力略有升高、持粘力明显下降。
The core/shell-acrylate emulsion coated by rosin derivatives for pressure sensitive adhesive （PSA） was prepared by mini-emulsion two-step method. The influences of some factors[such as mini-emulsion polymerization conditions, and hydrogenated rosin diglycol ester（HR-DGE） contentslon the properties of emulsion and its PSA were emphatically discussed. The research results showed that the optimal polymerization conditions of emulsion for PSA were obtained, which monomer conversion （above 95% ） was relatively highest, when mass fractions of HR-DGE and APS were 5% and 0.8% respectively in total monomers, and heat preservation time and temperature were 2-3 h and 85 ℃ respectively. The PSA had the good initial tack and hold tack when mass fraction of HR-DGE was 4%. With increasing HR-DGE, the wettability of emulsion for PSA on BOPP film was increased, the relative molecular mass （Mr） was decreased, the distribution of Mr was narrow and the glass transition temperature （Tg） had the trend of fall-rise, and the initial tack of PSA was slightly rise but the hold tack was obviously decreased.