文献类型：期刊文献

英文题名：Synthesis and bulk polymerization kinetics of monomer dehydroabietic acid-(2-acryloyloxy-ethoxy)-ethyl ester

作者：Zhang, Haibo[1] Yang, Yanping[1] Liu, He[1] Song, Jie[2] Shang, Shibin[1,3] Song, Zhanqian[1,3]

第一作者：张海波

通信作者：Shang, SB[1];Shang, SB[2]

机构：[1]Chinese Acad Forestry, Natl Engn Lab Biomass Chem Utilizat, Key & Open Lab Forest Chem Engn,State Forestry Ad, Key Lab Biomass Energy & Mat,Inst Chem Ind Forest, Nanjing 210042, Jiangsu, Peoples R China;[2]Univ Michigan Flint, Dept Chem & Biochem, Flint, MI 48502 USA;[3]Chinese Acad Forestry, Inst New Technol Forestry, Beijing 100091, Peoples R China

年份：2017

卷号：4

期号：1

起止页码：97-105

外文期刊名：FRONTIERS OF AGRICULTURAL SCIENCE AND ENGINEERING

收录：Scopus(收录号：2-s2.0-85028848151);WOS:【ESCI(收录号:WOS:000407141500009)】；

基金：This study was supported by the National Natural Science Foundation of China (31470597).

语种：英文

外文关键词：dehydroabietic acid; bulk polymerization; kinetics; autocatalytic kinetic model

摘要：A bulk polymerization monomer dehydroabietic acid-(2-acryloyloxy-ethoxy)-ethyl ester (DHA-DG-AC) was synthesized from dehydroabietic acid (DHA). The chemical structure of DHA-DG-AC was characterized by H-1 NMR, C-13 NMR, MS and FT-IR. The kinetics of the bulk polymerization of DHA-DG-AC was investigated by Differential Scanning Calorimeter (DSC). Two kinds of kinetic model (nth-order model and autocatalytic model) were used to investigate the polymerization process. The results showed that the experimental DSC curves were consistent with the computational data generated by the autocatalytic kinetic model, and the value of E-a was 95.73 kJ.mol(-1).