文献类型：期刊文献

英文题名：Selective cleavage of ester linkages of anhydride-cured epoxy using a benign method and reuse of the decomposed polymer in new epoxy preparation

作者：Liu, Tuan[1] Guo, Xiaolong[1] Liu, Wangcheng[1] Hao, Cheng[1] Wang, Liwei[1] Hiscox, William C.[2] Liu, Chengyun[1] Jin, Can[1,3] Xin, Junna[1] Zhang, Jinwen[1]

第一作者：Liu, Tuan

通信作者：Zhang, JW[1]

机构：[1]Washington State Univ, Composite Mat & Engn Ctr, Sch Mech & Mat Engn, Pullman, WA 99164 USA;[2]Washington State Univ, Nucl Magnet Resonance Ctr, Pullman, WA 99164 USA;[3]Chinese Acad Forestry, Inst Chem Ind Forest Prod, Nanjing 210042, Jiangsu, Peoples R China

年份：2017

卷号：19

期号：18

起止页码：4364-4372

外文期刊名：GREEN CHEMISTRY

收录：;Scopus(收录号：2-s2.0-85029871979);WOS:【SCI-EXPANDED(收录号:WOS:000411285400016)】；

基金：The authors are grateful for the financial support from the Joint Center for Aerospace Technology Innovation (JCATI).

语种：英文

摘要：Thermosetting polymers possess high dimensional stability, chemical resistance and thermal stability, and they are indispensable for many applications. However, conventional thermosetting polymers cannot be reprocessed and reshaped due to their permanent cross-linked structure. Therefore, recycling of thermosetting polymers is a serious challenge. Degrading thermosetting polymers into soluble oligomers and reuse of the oligomers in new resin systems may provide a favorable way to solve this problem. In this work, we developed an efficient method for chemical degradation of anhydride-cured epoxy using environmentally benign phosphotungstic acid (HPW) aqueous solution as the catalyst system at a mild reaction temperature of 190 degrees C. During reaction, the ester bond in the cross-linked structure was selectively cleaved, and the thermosetting polymer was fully converted to oligomers that contain multifunctional reactive groups. When the decomposed matrix polymer (DMP) was used as a reactive ingredient and added up to 40 wt% in the preparation of a new anhydride-cured epoxy curing system, the resulting cross-linked polymers still retained the mechanical properties of the neat polymer.