文献类型：期刊文献

英文题名：Integrated lignocellulosic biorefinery for efficient production of furans and photothermal materials

作者：Liu, Chao[1,2] Wang, Kui[1,2] Zhao, Xinpeng[3,4] Chen, Zhijun[3,4] Yin, Xiaoyan[1] Cai, Tingting[1] Zhang, Xiaolei[5] Xu, Junming[1,2] Hu, Jun[6] Meng, Xianzhi[7] Ragauskas, Arthur J.[7,8,9] Jiang, Jianchun[1,2]

第一作者：Liu, Chao

通信作者：Wang, K[1];Jiang, JC[1];Chen, ZJ[2];Chen, ZJ[3];Ragauskas, AJ[4]

机构：[1]Chinese Acad Forestry, Inst Chem Ind Forest Prod, Key Lab Biomass Energy & Mat, Natl Engn Lab Biomass Chem Utilizat, Nanjing 210042, Jiangsu, Peoples R China;[2]Nanjing Forestry Univ, Coinnovat Ctr Efficient Proc & Utilizat Forest Res, Nanjing 210037, Peoples R China;[3]Northeast Forestry Univ, Engn Res Ctr Adv Wooden Mat, Harbin 150040, Peoples R China;[4]Northeast Forestry Univ, Key Lab Biobased Mat Sci & Technol, Minist Educ, Harbin 150040, Peoples R China;[5]Univ Strathclyde, Dept Chem & Proc Engn, Glasgow City G1 1XJ, Scotland;[6]Northwest Univ, Sch Chem Engn, Xian 710069, Peoples R China;[7]Univ Tennessee, Dept Chem & Biomol Engn, Knoxville, TN 37996 USA;[8]Oak Ridge Natl Lab, Joint Inst Biol Sci, Biosci Div, Oak Ridge, TN 37831 USA;[9]Univ Tennessee, Ctr Renewable Carbon, Dept Forestry Wildlife & Fisheries, Inst Agr, Knoxville, TN 37996 USA

年份：2023

卷号：453

外文期刊名：CHEMICAL ENGINEERING JOURNAL

收录：;EI(收录号：20224513072056);Scopus(收录号：2-s2.0-85141252235);WOS:【SCI-EXPANDED(收录号:WOS:000892205700003)】；

基金：The authors would like to thank National Nature Science Foundation of China (31870714) , and the Youth Talent Support Program for Science & Technology Innovation of National Forestry and Grassland (2019132603) for financial support. Natural Science Funding of Heilong Jiang province for Excellent Young Scholar (YQ2020C017) . The work was carried out at Shanxi Supercomputing Center of China, and the calculations were performed on TianHe-2.

语种：英文

外文关键词：Lignocellulosic biomass; Molten salt hydrate; Solvent effects; Photothermal materials

摘要：Integrated lignocellulosic biorefineries offer a great potential to valorize all the components in lignocellulose into products, including fuels, chemicals, and materials. However, because of lignocellulose recalcitrance, conversion of bioresources remains a techno-economic challenge for many lignocellulosic biorefineries. In this work, we have proposed a sustainable and profitable biorefinery strategy for lignocellulose fractionation and conversion. In this design, a biphasic solvent consisting of a molten salt hydrate LiCl center dot H2O and gamma-valerolactone (GVL) was initially used for separating hemicellulose from lignocellulose. More interestingly, 100 wt% of biorefinery products from lignin were directly converted to functional photothermal materials by coordinating with Fe3+ for solar-thermal-electricity conversion. Attributed to this rational design, the techno-economic analysis predicts a revenue of 439.3 USD by processing 100 kg of lignocellulosic biomass using the above developed method.