文献类型：期刊文献

英文题名：Research Progress of Bio-Based Polybenzoxazine Materials

作者：Zhou, Xuan[1,2] Fu, Fei[1,3] Shen, Minggui[1] Li, Qiaoguang[4] Liu, He[1] Song, Zhanqian[1]

第一作者：Zhou, Xuan

通信作者：Shen, MG[1];Song, ZQ[1];Li, QG[2]

机构：[1]Chinese Acad Forestry, Inst Chem Ind Forestry Prod, Nanjing 210042, Jiangsu, Peoples R China;[2]Nanjing Forestry Univ, Coll Chem Engn, Jiangsu Coinnovat Ctr Efficient Proc & Utilizat Fo, Nanjing 210037, Peoples R China;[3]Henan Univ Technol, Coll Adv Interdisciplinary Sci & Technol, 100 Lianhua St, Zhengzhou 450001, Peoples R China;[4]Zhongkai Univ Agr & Engn, Coll Chem & Chem Engn, Guangzhou 510225, Guangdong, Peoples R China

年份：2023

外文期刊名：ADVANCED SUSTAINABLE SYSTEMS

收录：;EI(收录号：20234114854515);Scopus(收录号：2-s2.0-85173461432);WOS:【SCI-EXPANDED(收录号:WOS:001075393400001)】；

基金：This work was supported by the National Natural Science Foundation of China (32271816) and Key R & D Projects of Guangxi Zhuang Autonomous Region (No. AB20238008).

语种：英文

外文关键词：bio-based materials; polybenzoxazines; renewable resources; synthesis; thermosetting resins

摘要：As a new type of thermosetting resin, polybenzoxazine resin (PBz) has the advantages of flexible molecular design, excellent thermal stability, and mechanical properties. It has application potential in many fields such as aerospace, hydrophobic flame retardant, anti-corrosion, antibacterial, and electronic communication. Unlike traditional thermosetting resins, PBz can be made with natural renewable resources in addition to petrochemical raw materials. At present, PBz has synthesized monomers from renewable resources and made breakthroughs in raw material sources and performance improvement. In this work, the preparation methods and research progress of bio-based benzoxazine (BOZ) with different phenol sources and amine sources in the past 10 years are reviewed. The existing shortcomings and improvement methods of PBz functional materials are analyzed, and the future research direction of bio-based PBz is prospected. Bio-based polybenzoxazines (PBz) almost cover all the functions and applications of petroleum-based PBz. In recent years, bio-based PBz has made major breakthroughs in raw material sources and performance improvement. In this work, the methods and research progress of preparing bio-based PBz from different bio-based phenolic sources and amine sources in the past ten years are reviewed.image