文献类型：期刊文献

英文题名：Hydrodeoxygenation of biomass derivatives: A review on ruthenium-based catalysts and their performance

作者：Zhang, Kaili[1,2] Tao, Ran[2] Zhang, Ning[2] Wang, Kui[2] Jiang, Jianchun[1,2]

第一作者：Zhang, Kaili

通信作者：Zhang, KL[1];Jiang, JC[1];Zhang, KL[2];Jiang, JC[2]

机构：[1]Nanjing Forestry Univ, Coll Chem Engn, Jiangsu Coinnovat Ctr Efficient Proc & Utilizat Fo, Int Innovat Ctr Forest Chem & Mat, Nanjing 210037, Peoples R China;[2]Chinese Acad Forestry, Inst Chem Ind Forest Prod, Jiangsu Coinnovat Ctr Efficient Proc & Utilizat Fo, Key Lab Biomass Energy & Mat, Nanjing 210042, Jiangsu, Peoples R China

年份：2025

卷号：587

外文期刊名：MOLECULAR CATALYSIS

收录：;EI(收录号：20253819191864);Scopus(收录号：2-s2.0-105016267218);WOS:【SCI-EXPANDED(收录号:WOS:001576800000001)】；

基金：This work was supported by National Natural Science Foundation of China (22408175) , National Key R & D Program of China (2024YFD2200800) and the Research Start-up Funding of Nanjing Forestry University (163030305) .

语种：英文

外文关键词：Ru catalyst; Biomass derivatives; Hydrodeoxygenation; Valorization

摘要：Hydrodeoxygenation (HDO) is a key catalytic process for upgrading biomass derivatives into high-value biofuels and chemicals, providing a sustainable alternative to fossil fuel-based production. Among numerous catalytic systems, ruthenium (Ru)-based catalysts have attracted considerable attention due to their excellent activity, selectivity, and stability in cleaving C-O bonds under relatively mild reaction conditions. This review comprehensively summarizes the recent research progress in the application of Ru-based catalysts for the HDO of various biomass derivatives, including furans, carboxylic acids, and phenolics. We systematically discuss the influence of Ru-based catalyst design parameters (such as metal particle size, electronic state, and support properties) on the directed HDO of biomass derivatives. In addition, this review elaborates on the possible reaction mechanisms of Ru-based catalysts in the HDO process. Finally, the challenges and opportunities faced in this interesting and important research field are prospected, aiming to promote the practical application of Ru-based catalysts in sustainable biomass conversion.