文献类型：期刊文献

英文题名：Electrochemical Synthesis of β-Keto Sulfonyl Fluorides via Radical Fluorosulfonylation of Vinyl Acetates

作者：Feng, Qingyuana[1,2] He, Tianyu[2] Li, Shuohaia[1] Mei, Li[1] Huang, Shenlin[2]

第一作者：Feng, Qingyuana

通信作者：Mei, L[1];Huang, SL[2]

机构：[1]Chinese Acad Forestry, Inst Chem Ind Forest Prod, Nanjing 210042, Peoples R China;[2]Nanjing Forestry Univ, Coll Chem Engn, Jiangsu Coinnovat Ctr Efficient Proc & Utilizat Fo, Nanjing 210037, Peoples R China

年份：2025

卷号：45

期号：10

外文期刊名：CHINESE JOURNAL OF ORGANIC CHEMISTRY

收录：;WOS:【SCI-EXPANDED(收录号:WOS:001613635700027)】；

基金：Project supported by the Fundamental Research Funds of the Chinese Academy of Forestry (No. CAFYBB2024MA030) and the National Natural Science Foundation of China (No. 32171724) .

语种：英文

外文关键词：electrochemistry; sulfonyl fluorides; vinyl acetates; fluorosulfonyl radicals

摘要：beta-Keto sulfonyl fluorides were synthesised under electrochemical conditions using vinyl acetate with sulfuryl chlorofluoride. The electroreductive strategy requires neither sacrificial electrodes nor metal catalysts, and thus features mild conditions with wide substrate scope, enabling the synthesis of various beta-keto sulfonyl fluorides from simple ketone feedstocks. Moreover, this transformation can be perfomed in continuous flow reactor.