文献类型：期刊文献

英文题名：The Effects of Epoxidized Acrylated Castor Oil (EACO) on Soft Poly (vinyl chloride) Films as a Main Plasticizer

作者：Song, Fei[1,2,4] Xia, Haoyu[3] Jia, Puyou[1,2,4] Zhang, Meng[1,2,4] Hu, Lihong[1,2,4] Zhou, Yonghong[1,2,4]

第一作者：Song, Fei

通信作者：Jia, PY[1];Zhou, YH[1];Jia, PY[2];Zhou, YH[2];Jia, PY[3];Zhou, YH[3]

机构：[1]Chinese Acad Forestry, State Forestry Adm, Inst Chem Ind Forest Prod, Natl Engn Lab Biomass Chem Utilizat,Key Lab Fore, 16 Suojin North Rd, Nanjing 210042, Jiangsu, Peoples R China;[2]Key Lab Biomass Energy & Mat, 16 Suojin North Rd, Nanjing 210042, Jiangsu, Peoples R China;[3]Nanjing Tech Univ, Coll Chem Engn, 30 Pu Zhu Rd, Nanjing 211800, Jiangsu, Peoples R China;[4]Nanjing Forestry Univ, Coinnovat Ctr Efficient Proc & Utilizat Forest Re, Nanjing 211800, Jiangsu, Peoples R China

年份：2018

卷号：20

期号：4

起止页码：13-19

外文期刊名：POLISH JOURNAL OF CHEMICAL TECHNOLOGY

收录：;Scopus(收录号：2-s2.0-85058812883);WOS:【SCI-EXPANDED(收录号:WOS:000455497100003)】；

基金：This work was supported by the National Natural Science Foundation of China (Grant Nos. 31700499, 31670577 and 31670578), the Fundamental Research Funds for the Central Non-profit Research Institution of CAF (CAFYBB2018QB008), and the Fundamental Research Funds from Jiangsu Province Biomass and Materials Laboratory (JSBEM-S-2017010).

语种：英文

外文关键词：Castor Oil; Poly(vinyl chloride); Epoxy Plasticizer; Thermal Property; Migration Resistance

摘要：In this work, an environmentally friendly type plasticizer was introduced. The synthesis consisted of two steps. In the first step, castor oil (CO) was acrylated and then the acrylated castor oil (ACO) was epoxidized with the presence of formic acid and hydrogen peroxide in the second step. The epoxidized acrylated castor oil (EACO) was characterized by FT.IR and H-1-NMR techniques. The EACO was used as a main plasticizer to obtain plasticized PVC materials and compared with.DOP The results showed that EACO improved polyvinyl-chloride (PVC) plasticization perfot mance and reduced Tg from 81.06 C to 11.40 C. Plasticized PVC materials with-EACO showed similar mechanical properties and better thermal stability than DOP. I:ACO had better volatility stabilities, migration and solvent extraction in PVC than.DOP EACO can be used to replace DOP to prepare soft films.