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稻壳快速热解制备生物油条件探索及产物分析     被引量:5

Conditions of Rice Husk Fast Pyrolysis in Fluidized Bed and Its Product Analysis

文献类型:期刊文献

中文题名:稻壳快速热解制备生物油条件探索及产物分析

英文题名:Conditions of Rice Husk Fast Pyrolysis in Fluidized Bed and Its Product Analysis

作者:徐俊明[1,2,3,4] 戴伟娣[1,2,3,4] 许玉[1,2,3,4] 蒋剑春[1,2,3,4]

第一作者:徐俊明

机构:[1]中国林业科学研究院林产化学工业研究所;[2]中国林业科学院林业新技术研究所生物质化学利用国家工程实验室;[3]国家林业局林产化学工程重点开放性实验室;[4]江苏省生物质能源与材料重点实验室

年份:2011

卷号:45

期号:4

起止页码:23-26

中文期刊名:生物质化学工程

外文期刊名:Biomass Chemical Engineering

基金:国家林业局公益性行业专项(200904008)

语种:中文

中文关键词:稻壳;热解;生物油

外文关键词:rice husk; pyrolysis; bio-oil

分类号:TQ351

摘要:以稻壳为原料,通过流化床快速热解的方式制备生物油。初步考察了螺旋进料速率对流化床反应参数的影响。当进料速率由4kg/h提高至5kg/h时,床层温度明显下降,床层压差明显增加,燃气流量也明显增加,表明热解产物更多地发生了二次裂解反应。采用GC-MS对快速热解所得生物油的组成进行分析,采用TG—DSC考察生物油的热稳定性,表明在250—400℃之间,出现较强的放热现象,缩聚现象严重,并对其重要的燃料性能进行表征,pH值2.33,水分24.0%,热值16.3MJ/kg,密度1.17g/mL,黏度45mm2/s(30℃)。
Bio-oil from rice husk was prepared by fast pyrolysis. The effect of feed rate on the reaction parameters of fluidized reactor was investigated. With increasing feed rate (4 kg/h to 5 kg/h) it was found that the pressure difference and pyrolysis gas were also increased, while reaction temperature decreased. These results indicated that secondly-cracking reaction was increased in pyrolytic products. The components of product were analysized by GC-MS. Thermal stability of bio-oil was determined by TG-DSC. The major fuel properties of bio-oil were characterized.

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