文献类型：期刊文献

英文题名：Green Synthesis and Characterization of Gold Nanoparticles Using Lignin Nanoparticles

作者：Wang, Baobin[1] Yang, Guihua[1] Chen, Jiachuan[1] Fang, Guigan[2]

第一作者：Wang, Baobin

通信作者：Yang, GH[1];Fang, GG[2]|[a000589b6171897e30b38]房桂干;

机构：[1]Qilu Univ Technol, State Key Lab Biobased Mat & Green Papermaking, Shandong Acad Sci, Jinan 250353, Peoples R China;[2]Chinese Acad Forestry, Inst Chem Ind Forest Prod, Nanjing 210042, Peoples R China

年份：2020

卷号：10

期号：9

起止页码：1-12

外文期刊名：NANOMATERIALS

收录：;Scopus(收录号：2-s2.0-85091119575);WOS:【SCI-EXPANDED(收录号:WOS:000581351800001)】；

基金：The authors are grateful for the financial support from the National Key Research and Development Program of China (Grant No. 2017YFB0307900), the National Natural Science Foundation of China (Grant No. 31770628), the Provincial Key Research and Development Program of Shandong (Grant No. 2019JZZY010326), and the Taishan Scholars Program.

语种：英文

外文关键词：lignin nanoparticles (LNPs); gold nanoparticles (Au NPs); green synthesis; nanotechnology; functional material

摘要：With the development of nanotechnology, gold nanoparticles (Au NPs) have attracted enormous attention due to their special properties. The green synthesis of Au NPs from lignin would inspire the utilization of lignin and its related functional materials. In this study, a rapid preparation process of Au NPs was investigated by utilizing lignin nanoparticles (LNPs) under room temperature without chemical addition. The LNPs acted as a reducing agent, stabilizing agent, and template for the preparation of LNPs@AuNPs. The obtained LNPs@AuNPs were characterized by UV-Vis spectrum, Transmission Electron Microscope (TEM), and X-ray photoelectron spectroscopy (XPS). The possible mechanism was illustrated by Fourier Transform Infrared Spectroscopy (FT-IR), P-31, XPS, and UV analyses. The abundant hydroxyl groups (24.96 mmol/g) favored the preparation of Au NPs. Au NPs diameters of 10-30 nm were well dispersed in the LNPs. The optimal reaction conditions were a ratio of 10 mg of LNPs to 0.05 mmol HAuCl4, room temperature, and a reaction time of 30 min. The LNPs@AuNPs exhibited excellent stability in the suspension for more than seven days. The reduction process could be related to the disruption of side chains of lignin, hydroxyl group oxidation, and hydroquinones and quinones from the comproportionation reaction. The LNPs@AuNPs would open a door for the design of Au NP/lignin-derived novel functional materials.