文献类型：期刊文献

英文题名：Solvent and additive-free selective aerobic allylic hydroxylation of beta-pinene catalyzed by metalloporphyrins

作者：Xu, Shi-Chao[1,2,3,4,5,6] Zhu, Shou-Ji[1,2,3,4] Bi, Liang-Wu[1,2,3,4,5,6] Chen, Yu-Xiang[1,2,3,4,5] Wang, Jing[1,2,3,4] Lu, Yan-Ju[1,2,3,4,5] Gu, Yan[1,2,3,4] Zhao, Zhen-Dong[1,2,3,4,5,6]

第一作者：Xu, Shi-Chao;徐士超

通信作者：Zhao, ZD[1];Zhao, ZD[2];Zhao, ZD[3];Zhao, ZD[4];Zhao, ZD[5];Zhao, ZD[6]

机构：[1]Chinese Acad Forestry, Inst Chem Ind Forest Prod, Nanjing 210042, Jiangsu, Peoples R China;[2]Key Lab Biomass Energy & Mat, Nanjing 210042, Jiangsu, Peoples R China;[3]Natl Engn Lab Biomass Chem Utilizat, Nanjing 210042, Jiangsu, Peoples R China;[4]State Forestry Adm, Key & Open Lab Forest Chem Engn, Nanjing 210042, Jiangsu, Peoples R China;[5]Chinese Acad Forestry, Inst Forestry New Technol, Beijing 100091, Peoples R China;[6]Jiangxi Agr Univ, Collaborat Innovat Ctr Jiangxi Typ Trees Cultivat, Nanchang 330045, Jiangxi, Peoples R China

年份：2017

卷号：28

期号：3

起止页码：575-578

外文期刊名：CHINESE CHEMICAL LETTERS

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000395836200015)】；

基金：This work was funded by the Fundamental Research Funds for Jiangsu Key Lab of Biomass Energy and Material (No. JSBEM-S201605), the National Natural Science Foundation of China (No. 31600466) and the Fundamental Research Funds for the Central Non-profit Research Institution of CAF (No. CAFYBB2014QA022).

语种：英文

外文关键词：Turpentine transformation; beta-Pinene; Metalloporphyrin Biomimetic catalysis; Aerobic allylic hydroxylation

摘要：Metallodeuteroporphyrins (MDPs) were employed as the catalysts for aerobic oxidation of beta-pinene in absence of solvents and additives. Allylic hydroxylation products were found to be the main products from this protocol. The catalytic activity of MDPs with different metal nuclei and the influences of technological conditions on this reaction were investigated. This catalytic system has bright application prospect since only eco-friendly and readily available dioxygen were needed. (C) 2016 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.