文献类型：期刊文献

英文题名：Preparation and application of epoxy oil-based fire-retardant plasticiser with triazine ring structure (THEIC-SBOE)

作者：Feng, G. -D.[1,2] Hu, Y.[1] Zhou, Y. -H.[1,3]

第一作者：冯国东;Feng, G. -D.

通信作者：Zhou, YH[1]

机构：[1]Chinese Acad Forestry, Inst Chem Ind Forestry Prod, Nanjing 210042, Jiangsu, Peoples R China;[2]Jiangsu Qianglin Bioenergy & Biomat Ltd Co, Li Yang 213364, Jiangsu, Peoples R China;[3]Chinese Acad Forestry, Inst New Technol Forestry, Beijing 100091, Peoples R China

年份：2015

卷号：19

起止页码：481-485

外文期刊名：MATERIALS RESEARCH INNOVATIONS

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000355379900095)】；

基金：The authors would like to thank the 'State '12th Five Year Plan' Science and Technology Support Plan' (2012BAD32B05) and the 'Commonwealth Research of CAF' (CAFINT2013K01) for financial support during this investigation.

语种：英文

外文关键词：Epoxy oil-based; Fire-retardant; Plasticiser; Poly (vinyl chloride); Limiting oxygen index

摘要：An epoxy oil-based fire-retardant plasticiser with a triazine ring structure [tris(2-hydroxyethyl) isocyanurate-soybean oil emulsion (THEIC-SBOE)] has been prepared by transesterification and epoxidation using tris(2-hydroxyethyl) isocyanurate and soybean oil methyl ester as the main raw materials. The structure of THEIC-SBOE has been characterised by Fourier transform infrared, H-1-NMR and C-13-NMR spectroscopies and elemental analysis, and its thermal stability has been measured by thermogravimetric analysis. Its epoxy value and acid value have been determined as 4.3% and 0.60 mg.KOH g(-1), respectively. Examination of the morphology of carbon residue from poly (vinyl chloride) by scanning electron microscopy showed THEIC-SBOE to serve as an intumescent flame retardant. The results showed that, with the same plasticiser contents incorporated into poly (vinyl chloride), THEIC-SBOE imparted similar mechanical properties as epoxidised soybean oil. Furthermore, poly (vinyl chloride) blends incorporating the synthesised plasticiser THEIC-SBOE displayed better fire-retardant properties than those incorporating dioctyl phthalate. The limiting oxygen index of such a poly (vinyl chloride) blend reached 28.4 with 35% (w/w) THEIC-SBOE incorporation.