文献类型：期刊文献

英文题名：N-(2-Pyridylmethyleneamino)dehydroabietylamine

作者：Wu, Yong[1,2] Rao, Xiao-Ping[1] Wang, Zong-De[2] Song, Zhan-Qian[1] Yao, Xu-Jie[2]

第一作者：Wu, Yong

通信作者：Rao, XP[1]|[a0005b2996927fc131f05]饶小平;

机构：[1]Chinese Acad Forestry, Inst Chem Ind Forest Prod, Nanjing 210042, Peoples R China;[2]Jiangxi Agr Univ, Coll Landscape Architecture & Art, Nanchang 330045, Peoples R China

年份：2009

卷号：65

期号：4

起止页码：O786-U2258

外文期刊名：ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000264798500204)】；

基金：This research was supported by grants from the National Natural Science Foundation of China (grant No. 30771690) and the Forestry Commonwealth Industry Special Foundation of China (grant No. 200704008).

语种：英文

摘要：The title compound {systematic name: 1-[(1R,4aS,10aR)-7-isopropyl- 1,2,3,4,4a,9,10,10a-octahydrophenanthren-1-yl]-N-[(E)-2-pyridylmethyleneamino]methanamine}, C26H33N2, has been synthesized from dehydroabietylamine. The two cyclohexane rings form a trans ring junction with classic chair and half-chair conformations, respectively, whereas the benzene and pyridine rings are almost planar, and the dihedral angle between them is 80.4 degrees. The two methyl groups directly attached to the tricyclic nucleus are on the same side of the tricyclic hydrophenanthrene structure.