文献类型：期刊文献

英文题名：Synthesis and Crystal Structure of Fumaropimaric Acid Triacid Amide

作者：Song, Xing[1] Zhou, Yonghong[1] Zhang, Meng[1] Yang, Xiaohui[1]

第一作者：Song, Xing

通信作者：Zhou, YH[1]

机构：[1]Chinese Acad Forestry, Inst Chem Ind Forest Prod, Nanjing 210042, Peoples R China

年份：2011

卷号：23

期号：4

起止页码：1838-1840

外文期刊名：ASIAN JOURNAL OF CHEMISTRY

收录：;Scopus(收录号：2-s2.0-79952153719);WOS:【SCI-EXPANDED(收录号:WOS:000288465100103)】；

基金：This work was supported by the "948" program of the State Forestry Administration (2009-4-55), The President of the Chinese Academy of Forestry Foundation (CAFYBB2008009), National Significant Industry and Technology Special Projects (High-tech Development and Reform Commission [2008] No. 2441).

语种：英文

外文关键词：Fumaropimaric acid triacid amide; Synthesis; Crystal structure

摘要：The compound fumaropimaric acid triacid amide was synthesized by acyl chlorination and ammonolysis reaction between fumaropimaric acid and SOCI2 and aqueous ammonia. It was characterized by single crystal X-ray diffraction. The colourless crystals crystallized in the orthorhombic system, space group P2(12121) with cell dimensions: a = 7.2910(15) angstrom, b = 15.221(3) angstrom, c = 21.822(4) angstrom, alpha = 90 degrees, beta = 90 degrees, gamma = 90 degrees, V = 2421.7(8) angstrom(3) and R-1 = 0.0645, wR(2) = 0.1404. The two fused and unbridged cyclohexane rings have chair conformations. The other rings are twist-boat forms. The molecular structure includes two molecules (fumaropimaric acid triacid amide and methanol). The I molecules are linked by hydrogen bonds and van der Waals forces. The crystal structure has been deposited at the Cambridge crystallographic I data centre and allocated the deposition number CCDC 790373.