文献类型：期刊文献

中文题名：生物质二氧化碳气化综述

英文题名：A Review of Biomass Carbon Dioxide Gasification

作者：王燕杰[1,2,3,4] 应浩[1,2,3,4,5] 江俊飞[1,2,3,4]

第一作者：王燕杰

通信作者：Ying, H.|[a00053bb06bfd548b597c]应浩;

机构：[1]中国林业科学研究院林产化学工业研究所;[2]生物质化学利用国家工程实验室;[3]国家林业局林产化学工程重点开放性实验室;[4]江苏省生物质能源与材料重点实验室;[5]中国林业科学研究院林业新技术研究所

年份：2013

卷号：33

期号：6

起止页码：121-127

中文期刊名：林产化学与工业

外文期刊名：Chemistry and Industry of Forest Products

收录：CSTPCD;;EI(收录号：20140417230848);Scopus(收录号：2-s2.0-84892506489);北大核心:【北大核心2011】；CSCD:【CSCD2013_2014】；

基金：'十二五'国家科技支撑计划资助(2012BAA09B03)

语种：中文

中文关键词：生物质;二氧化碳;气化;压力;催化

外文关键词：biomass; carbon dioxide; gasification; pressure; catalysis

分类号：TQ35

摘要：综述了温度、压力、催化剂和产物中CO的浓度等因素对生物质在CO2气氛中气化的影响。提高反应温度可以明显增加反应速率;压力的作用较复杂,反应过程中不仅受总压力的影响还受到反应物分压的影响;碱金属元素和碱土金属可以促进反应;根据反应机理,气体中CO含量过高会抑制反应的进行,减少反应中CO的分压和含量可以促进反应。展望了生物质CO2气化的应用前景。
The effect of temperature,pressure,catalyst and the concentration of monoxide on biomass carbon dioxide gasification was reviewed.With the increment of temperature,the reactivity of biomass was accelerated dramatically.The effect of the pressure was complex for the reaction of gasification.It was influenced both by partial pressure of components and the whole pressure.Alkali metal and alkali earth metal can be used as catalysts for accelerating the reaction of biomass carbon dioxide gasification.According to the mechanism of carbon dioxide gasification,increasing the amount of monoxide inhibits the reaction to the favorable side.However,reducing the partial pressure and the amount of monoxide in the syngas can promote the reaction rate.The prospect of biomass carbon dioxide gasification application was also presented.