文献类型：期刊文献

英文题名：Mechanical properties of wood flour/poly (lactic acid) composites coupled with waterborne silane-polyacrylate copolymer emulsion

作者：Liu, Ru[1,2] Luo, Shupin[1] Cao, Jinzhen[1] Chen, Yu[1]

第一作者：Liu, Ru;刘如

通信作者：Cao, JZ[1]

机构：[1]Beijing Forestry Univ, MOE Key Lab Wooden Mat Sci & Applicat, Qinghua East Rd 35, Beijing 100083, Peoples R China;[2]Chinese Acad Forestry, Res Inst Wood Ind, Beijing 100091, Peoples R China

年份：2016

卷号：70

期号：5

起止页码：439-447

外文期刊名：HOLZFORSCHUNG

收录：;EI(收录号：20162002400286);Scopus(收录号：2-s2.0-84966936687);WOS:【SCI-EXPANDED(收录号:WOS:000375131700007)】；

基金：This study was financially supported by the National Natural Science Foundation of China (No. 31170524).

语种：英文

外文关键词：coupling agent; mechanical properties; polyacrylate emulsion; silane; wood-plastic composites

摘要：Wood flour/polylactic acid (WF/PLA) composites were produced with a WF content of 50% based on three types of waterborne polyacrylate (PA) emulsions including a PA homopolymer emulsion and two types of silane-PA copolymer emulsions as coupling agents. Two silanes were in focus, namely, gamma-methacryloxypropyl-trimethoxysilane (silane-1) and vinyltrimethoxysilane (silane-2). The emulsions and the modified WFs were characterized, and the effects were investigated in terms of emulsion type and their loading levels on the mechanical properties of WF/PLA composites. (1) Both types of silanes could be successfully copolymerized with PA to form stable emulsions. (2) With increasing PA loading, the mechanical properties (except for flexural modulus) of the composites increased at first before reaching the maximum values at 4% PA loading and then the properties worsened. However, these values were larger than those of pure composites, especially in cases when PA-silane emulsions were applied. (3) PA modified with silane-1 showed the best coupling effect among all the three PA emulsions. The results can be interpreted that PA emulsions are effective coupling agents for the preparation of high-performance WPCs.