文献类型：期刊文献

英文题名：Catalytic Conversion of Bamboo Meal to High-Yield Furfural With Solid Acid Catalyst FePO4 center dot 2H(2)O

作者：Ye, Jun[1,2] Zhou, Minghao[2] Wang, Kui[2] Chen, Shuigen[2] Xu, Junming[1] Jiang, Jianchun[2]

第一作者：叶俊

通信作者：Xu, JM[1];Jiang, JC[2]

机构：[1]Chinese Acad Forestry, Inst New Technol Forestry, Beijing 100091, Peoples R China;[2]Chinese Acad Forestry, Inst Chem Ind Forest Prod, Nanjing 210042, Jiangsu, Peoples R China

年份：2017

卷号：2

期号：34

起止页码：11250-11254

外文期刊名：CHEMISTRYSELECT

收录：;WOS:【SCI-EXPANDED(收录号:WOS:000417743100044)】；

基金：This work was supported by the Fundamental Research Funds of Research Institute of Forest New Technology (No: CAFYBB2016SY028), National Natural Science Foundation of China (31530010), "Research Grant of Jiangsu Province Biomass Energy and Materials Laboratory" (JSBEM-S-201701, JSBEM-S-201502, JSBEM-S-201607) and Natural Science Foundation of Jiangsu Province" (No. BK20151068).

语种：英文

外文关键词：Bamboo mea; Furfural; H2O; THF; FePO4 center dot H2O

摘要：Furfural has been identified as an attractive platform chemical for production of valuable bio-based chemicals and bio-fuels. Therefore, to exploit a new catalyst which directly synthesized furfural from biomass was meaningful. In this work, FePO(4)2H(2)O was novelty applied in H2O/THF solvent system to produce furfural from bamboo meal. The influence of catalyst type, solvent type, catalyst dosage, reaction temperature and times on furfural production was comparatively evaluated. The results indicated that the FePO4 catalyst displayed an excellent catalytic activity over mineral acids, metal chlorate and solid acids, achieving the highest furfural yield of 90.5% (from d-xylose) and 83.1mol % (from bamboo meal) at 170 degrees C (60min) and 180 degrees C (60min), respectively. Moreover, characterization indicated that FePO4 can recrystallize after the reaction, which provided a convenience for the catalyst recovery. Considering the excellent catalytic activity and recovering characteristic of FePO4 catalyst, systematical research of this new technique was required before the process could be considered as an industrial scale.