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On the palladium-on-charcoal disproportionation of rosin     被引量:14

文献类型:期刊文献

英文题名:On the palladium-on-charcoal disproportionation of rosin

作者:Song Z.-Q.[1] Zavarin E.[2] Zinkel D.F.[3]

第一作者:Song Z.-Q.

通信作者:Zavarin, E.[2]

机构:[1]Research Institute of Chemical Processing and Utilization of Forest Products, Chinese Academy of Forestry, Nanjing, China;[2]Forest Products Laboratory, University of California, Richmond, California, United States;[3]U.S.D.A. Forest Products Laboratory, Madison, Wisconsin, United States

年份:1985

卷号:5

期号:4

起止页码:535-542

外文期刊名:Journal of Wood Chemistry and Technology

收录:Scopus(收录号:2-s2.0-0022219580)

语种:英文

摘要:Changes in the composition of gum rosin during disproportionation in the presence of 5% palladium-on-charcoal have been determined by gas chromatography. The principal reaction product was dehydroabietic acid. The exocyclic vinyl group of the pimaric/isopimaric-type resin acids was hydrogenated completely. Only a small amount of dihydroabietic acids was formed. Eight dihydro resin acids were identified. No tetrahydro resin acids were observed. ? 1985, Taylor & Francis Group, LLC. All rights reserved.

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