文献类型：期刊文献

英文题名：A Promising Strategy for Solvent-Regulated Selective Hydrogenation of 5-Hydroxymethylfurfural over Porous Carbon-Supported Ni-ZnO Nanoparticles

作者：Huang, Rulu[1,2] Liu, Chao[3] Zhang, Kaili[2] Jiang, Jianchun[1,2] Tian, Ziqi[4] Chai, Yongming[5] Wang, Kui[1,2]

第一作者：Huang, Rulu

机构：[1] National Key Laboratory for Development and Utilization of Forest Food Resources, Biomass Energy and Material Key Laboratory of Jiangsu Province, Institute of Chemical Industry of Forest Products, Chinese Academy of Forestry, Nanjing, 210042, China; [2] Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, Nanjing Forestry University, Nanjing, 210037, China; [3] School of Materials Science and Engineering, Central South University of Forestry and Technology, Changsha, 410004, China; [4] Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo, 315201, China; [5] State Key Laboratory of Heavy Oil Processing, College of Chemistry and Chemical Engineering, China University of Petroleum [East China], Qingdao, 266580, China

年份：2026

卷号：18

期号：1

外文期刊名：Nano-Micro Letters

收录：EI(收录号：20253018830486);Scopus(收录号：2-s2.0-105011146785)

语种：英文

外文关键词：Catalyst activity - Catalyst supports - Hydrogenation - Metal nanoparticles - Nanocatalysts - Nickel compounds - Porous carbon - Porous materials - Solvents - Synthesis (chemical) - Temperature - ZnO nanoparticles

摘要：A porous carbon-supported Ni-ZnO nanoparticles catalyst (Ni-ZnO/AC) was synthesized by low-temperature coprecipitation, demonstrating exceptional catalytic activity and stability. Selective hydrogenation of 5-hydroxymethylfurfural (HMF) to 2,5-bis(hydroxymethyl)furan (97.5%) or 2,5-dimethylfuran (99.5%) is achieved over Ni-ZnO/AC catalyst by solvent-tuning. Solvent-catalyst interaction jointly regulates hydrodeoxygenation behavior in HMF hydrogenation by modulating rate and pathway via a hydrogen shuttle mechanism. ? The Author(s) 2025.