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Environmentally benign process for valorization of lignocellulosic bamboo residues with green solvent propylene carbonate  ( EI收录)  

文献类型:期刊文献

英文题名:Environmentally benign process for valorization of lignocellulosic bamboo residues with green solvent propylene carbonate

作者:Liang, Jie[1,2] Xie, Jingcong[1] Jiang, Jianchun[1,2] Ma, Yan[1] Ye, Jun[1] Zeng, Xianhai[3] Wang, Kui[1,2]

第一作者:Liang, Jie

机构:[1] Institute of Chemical Industry of Forest Products, Chinese Academy of Forestry, National Engineering Research Center of Low-Carbon Processing and Utilization of Forest Biomass, Nanjing, 210042, China; [2] Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, Nanjing Forestry University, Nanjing, 210037, China; [3] College of Energy, State Key Laboratory of Physical Chemistry of Solid Surfaces, Xiamen University, Xiamen, 361102, China

年份:2025

外文期刊名:Green Energy and Environment

收录:EI(收录号:20252718728235);Scopus(收录号:2-s2.0-105009687553)

语种:英文

外文关键词:Bamboo - Biodegradation - Carbonates - Green manufacturing - Lignin - Lignocellulose - Lignocellulosic biomass - Refining

摘要:A novel environmentally benign biphasic system composed of propylene carbonate (PC) and aqueous solution of p-toluenesulfonic acid (p-TsOH aq) was designed for the efficient valorization of lignocellulosic bamboo residues, resulting in more than 95.5% of hemicellulose and 97.2% of lignin digested under mild conditions of 130 °C for 1 h. Meanwhile, 91.9% of cellulose was retained with loose structure, followed by 95.8% enzyme hydrolysis yield and 347.9 mg g?1 of glucose yield. Notably, the synergistic effect between PC and p-TsOH on efficiency and selectivity was proposed by a control group experiment and subsequently verified, which is believed to be responsible for the simultaneous degradation and separation of lignin and hemicelluloses into oligomeric phenols and pentose, also facilitating subsequent valorization. Furthermore, the novel PC/p-TsOH aq biphasic system demonstrated excellent retrievability and adaptability to different feedstocks, offering a promising green strategy for the efficient valorization of lignocellulosic biomass in industrial biorefineries. ? 2025 Institute of Process Engineering, Chinese Academy of Sciences

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