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低温发泡制备酚醛泡沫材料及其表征     被引量:11

Preparation and characterization of phenolic foam used low-temperature foaming and curing method

文献类型:期刊文献

中文题名:低温发泡制备酚醛泡沫材料及其表征

英文题名:Preparation and characterization of phenolic foam used low-temperature foaming and curing method

作者:庄晓伟[1] 张伟[2] 王基夫[2] 李守海[2] 王春鹏[2] 储富祥[2]

第一作者:庄晓伟

机构:[1]浙江省林业科学研究院浙江省森林资源生物与化学利用重点实验室;[2]中国林业科学研究院林产化学工业研究所国家林业局林产化学工程重点开放性实验室

年份:2010

期号:S1

起止页码:144-148

中文期刊名:化工新型材料

外文期刊名:New Chemical Materials

收录:北大核心:【北大核心2008】;CSCD:【CSCD2011_2012】;

基金:国家863计划(2007AA100704);948重大项目(2006-4-C03);浙江省科技厅重大招标项目(2007C12018)

语种:中文

中文关键词:低温发泡;酚醛泡沫;力学性能;泡孔形态

外文关键词:low-temperature foaming and curing,phenolic foam,mechanical characterization,cell form

分类号:TQ328.1

摘要:采用40℃低温发泡的方法制备酚醛泡沫,研究了发泡剂、表面活性剂和固化剂对泡沫的表观密度和压缩强度的影响,讨论了低温发泡对泡沫力学性能、导热性能、泡孔形态、阻燃性能、微观结构和热稳定性的影响。试验结果表明,40℃低温发泡对酚醛泡沫的阻燃性和热稳定性影响较小,泡沫的韧性和脆性得到了明显改善,泡孔孔径更小、分布更加均匀。
In this paper,the phenolic foam is preparated by 40 degrees centigrade low-temperature foaming and curing method. The blowing agent,acid catalyst and effects of surfactant on apparent density and compressive strength were investigated according to variables of phenolic foam property. And the effects of low-temperature foaming and curing on mechanical characterization,heat insulation,cell form,fire-retardant,micro-structure and thermal stability was discussed.The results indicated that low-temperature foaming and curing was little effect on fire-retardant and thermal stability,and can improve the brittleness and flexibility of foam. The comprehensive performance of foam structure was the best,for example,the cell became smaller and distributed more uniformly.

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