文献类型：期刊文献

中文题名：湿法消解-石墨炉原子吸收光谱法测定山茶油中的镉

英文题名：Determination of Cadmium in Tea-Camellia Seed Oil by Wet Digestion-Graphite Furnace Atomic Absorption Spectrometry

作者：倪张林[1,2] 汤富彬[1,2] 屈明华[1,2] 沈丹玉[1,2] 莫润宏[1,2]

第一作者：倪张林

机构：[1]中国林业科学研究院亚热带林业研究所;[2]国家林业局经济林产品质量检验检测中心(杭州)

年份：2011

卷号：1

期号：3

起止页码：66-68

中文期刊名：中国无机分析化学

外文期刊名：Chinese Journal of Inorganic Analytical Chemistry

基金：中央级公益性科研院所基本科研业务费专项资金(RISF6151)

语种：中文

中文关键词：山茶油;镉;湿法;石墨炉原子吸收光谱法

外文关键词：tea-camellia seed oil; cadmium; wet digestion; graphite furnace atomic absorption spectrometry（GFAAS）

分类号：O657.31;TH744.125

摘要：《食用油卫生标准》GB2716-2005中对重金属铅和砷都有明确的限量规定（小于0.1 mg/kg）,但对于镉元素并没有限量规定。为此,选取目前较为热门的山茶油,建立硝酸和过氧化氢为酸体系,湿法消解-石墨炉原子吸收光谱法测定其中镉的含量,通过对山茶油的毛油和精炼油的测定,均有检出,与已报道的其它植物油中含量水平相当;方法的检出限为0.058μg/kg,RSD为12%,回收率为84%~103%。方法可靠,灵敏度高。
Although there is a clear definition for the threshold limit of lead （Pb） and arsenic（As） in vege- table oil which is d0.1 mg/kg in GB2716--2005,no threshold limit for cadmium was given in this standard. In this study, tea-camellia seed oil which is popularly studied was chosen and investigated. A new method using wet digestion-graphite furnace atomic absorption spectrometry was established in which HNO3 and H2O2 is used as the acidic system. The content of cadmium in the crude and refined tea-camellia seed oil were determined by the method. The results matched with those for other plant oils reported pre- viously. The detection limit, RSD and recovery rate of this method is 0. 058μg/L, 12%, and in the range of 84%-103%, respectively. Thus it concluded that this method is reliable and has high sensitivity.