文献类型：期刊文献

中文题名：漆酚缩水甘油醚的合成研究

英文题名：Study on the synthesis of urushiol glycidyl ether

作者：方传杰[1] 王成章[1,2] 周昊[1,2]

第一作者：方传杰

机构：[1]中国林业科学研究院林产化学工业研究所生物质化学利用国家工程实验室国家林业局林产化学工程重点开放性实验室江苏省生物质能源与材料重点实验室;[2]中国林业科学研究院林业新技术研究所

年份：2017

卷号：32

期号：3

起止页码：6-12

中文期刊名：热固性树脂

外文期刊名：Thermosetting Resin

收录：北大核心:【北大核心2014】；CSCD:【CSCD2017_2018】；

基金：江苏省生物质能源与材料重点实验室基本科研业务费(JSBEM-S-201509);国家自然科学基金(31570564)资助

语种：中文

中文关键词：漆酚;环氧氯丙烷;漆酚缩水甘油醚;环氧值;涂料;热稳定性

外文关键词：urushiol; epichlorohydrin; urushiolglycidylether; epoxidemumber; coating; thermal stability

分类号：TQ223.26

摘要：以漆酚(U)和环氧氯丙烷为原料制备了漆酚缩水甘油醚(UGE)。研究了反应物料比、反应时间、反应温度、催化剂和氢氧化钠用量等因素对UGE环氧值的影响,确定了最佳反应条件,并采用FT-IR、~1H-NMR、^(13)C-NMR、GPC和TG对产物的化学结构和热稳定性进行了分析。结果表明,目标产物已合成,其相对分子质量为478。产物的初始分解温度高达370℃,具有良好的热稳定性。其环氧值为0.305 mol/100 g,粘度为12.8 mPa·s(25℃)。与二乙烯三胺固化反应得到的漆膜硬度为H,并具有良好的弯曲性、耐冲击性、附着力和光泽度。
The urushiol glycidyl ether （UGE） was synthesized by using urushiol （U） and epichlorohydrin as raw materials. The effects of reaction material ratio, reaction time, reaction temperature, catalyst and sodium hydroxide dosages on the UGE epoxy value were investigated. The optimum reaction conditions were determined and the chemical structure and thermal stability of UGE were analyzed by FT-IR, 1H-NMR, 13C-NMR, GPC and TG. The results showed that the target product was synthesized. The relative molecular mass of UGE was 478. The initial decomposition temperature of UGE was up to 370 ℃ and had good thermal stability. The epoxy value of UGE was 0.309 tool/100 g and the viscosity was 12.8 mPa·s（25 ℃）. The UGE was cured with diethylenetriamine and the hardness of cured film was H. The film had good flexibility, impact resistance, adhesion and gloss.